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प्रश्न
What is the role of t-butyl peroxide in the polymerization of ethene?
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उत्तर
In polymerisation of ethene, source of free radical is needed to initiate the chain reaction. Such free radicals are usually produced by decomposition of peroxides like t-butyl peroxide or benzoyl peroxide.
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संबंधित प्रश्न
Write the molecular formula and structural formula of BHA and BHT.
Write the mechanism of free radical polymerization of ethene.
Write the free radical mechanism for the polymerisation of ethene.
Write chemical reaction to prepare the Dextron polymer:
Dextron
Why should the monomers used in addition polymerisation through free radical pathway be very pure?
Match the polymers given in Column I with their chemical names given in Column II.
| Column I | Column II |
| (i) Nylon 6 | (a) Polyvinyl chloride |
| (ii) PVC | (b) Polyacrylonitrile |
| (iii) Acrilan | (c) Polycaprolactum |
| (iv) Natural rubber | (d) Low-density polythene |
| (v) LDP | (e) cis-polyisoprene |
Assertion: Polytetrafluoroethene is used in making non-stick cookwares.
Reason: Fluorine has highest electronegativity.
Low density polythene and high density polythene, both are polymers of ethene but there is marked difference in their properties. Explain.
Which of the following is chain-growth polymer?
\[\ce{X + C + Cl2 ->[High temperature][of about 1000 K] Y + CO}\];
\[\ce{Y + 2H2O -> Z + 2HCl}\]
Compound Y is found in polymeric chain structure and is an electron-deficient Molecule. Y must be:
