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The rate constant for a first order reaction is 1.54 × 10−3 s−1. Calculate its half life time.

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प्रश्न

The rate constant for a first order reaction is 1.54 × 10−3 s−1. Calculate its half life time.

संख्यात्मक
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उत्तर

We know that `"t"_(1/2) = 0.693/"k"`

`"t"_(1/2) = 0.693/(1.54 xx 10^-3 "s"^-1)` = 450 s

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पाठ 7: Chemical Kinetics - Evaluation [पृष्ठ २३१]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
पाठ 7 Chemical Kinetics
Evaluation | Q 23. | पृष्ठ २३१

संबंधित प्रश्‍न

The rate constant for a first order reaction is 100 s–1. The time required for completion of 50% of reaction is _______.

(A) 0.0693 milliseconds

(B) 0.693 milliseconds

(C) 6.93 milliseconds

(D) 69.3 milliseconds


Which among the following reactions is an example of a zero order reaction?

a) `H_(2(g)) + I_(2(g)) -> 2HI_(g)`

b) `2H_2O_(2(l)) -> 2H_2O_(l) + O_(2(g))`

c) `C_12H_22O_(11(aq)) + H_2O_(l) -> C_6H_12O_(6(aq)) + C_6H_12O_(6(aq))`

d) `2NH_(3g)`   `N(2g) + 3H_(2(g))`


Show that the time required for 99% completion is double of the time required for the completion of 90% reaction.


The half life period of a first order reaction is 6. 0 h . Calculate the rate constant


In a first-order reaction A → product, 80% of the given sample of compound decomposes in 40 min. What is the half-life period of the reaction? 


The half life of the homogeneous gaseous reaction \[\ce{SO2Cl2 -> SO2 + Cl2}\] which obeys first order kinetics is 8.0 minutes. How long will it take for the concentration of SO2Cl2 to be reduced to 1% of the initial value?


Which radioactive isotope would have the longer half-life 15O or 19O? (Given rate constants for 15O and 19O are 5.63 × 10–3 s–1 and k = 2.38 × 10–2 s–1 respectively.)


The half-life of cobalt 60 is 5.26 years. The percentage activity remaining after 4 years is ______%.


The rate of a first order reaction is 0.04 mol litre-1 s-1 at 10 minutes and 0.03 mol litre-1 sec-1 at 20 minutes after initiation. The half-life of the reaction is ______ min.


Assertion (A): The half-life of a reaction is the time in which the concentration of the reactant is reduced to one-half of its initial concentration.

Reason (R): In first-order kinetics, when the concentration of reactant is doubled, its half-life is doubled.


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