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प्रश्न
Rita was given an unknown salt for identification. She prepared a solution of the salt and divided it into two parts.
- To the first part of the salt solution, she added a few drops of ammonium hydroxide and obtained a reddish-brown precipitate.
- To the second part of the salt solution, she added a few drops of silver nitrate solution and obtained a white precipitate.
Name:
- The cation present and
- The anion present in the salt given for identification.
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उत्तर
- Cation \[\ce{Fe^3+}\] (ferric ion)
When \[\ce{Fe^3+}\] reacts with \[\ce{NH4OH}\] it forms ferric hydroxide.
\[\ce{Fe^{3+} + 3NH4OH -> \underset{(Reddish brown ppt.)}{Fe(OH)3 + 3NH4^+}}\] - Anion: \[\ce{Cl−}\] (Chloride ion)
When \[\ce{Cl−}\] reacts with silver nitrate, it forms a white ppt. of silver chloride.
\[\ce{Cl- + AgNO3 - \underset{Silver chloride}{AgCl + NO^-3}}\]
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संबंधित प्रश्न
State your observations when ammonium hydroxide solution is added drop by drop and then in excess to each of the following solutions :
1) Copper sulphate solution
2) Zinc sulfate solution.
On adding dilute ammonia solution to a colourless solution of a salt, a white gelatinous precipitate appears. This precipitate however dissolves on addition of excess of ammonia solution. Identify (choose from Na, Al, Zn, Pb, Fe)
What is the formula of the white gelatinous precipitate obtained?
Name the metal hydroxides which are soluble in ammonium hydroxide solution.
Write the observation, and balanced equation for the following reaction:
Excess of ammonium hydroxide is added to a substance, obtained by adding hydrochloric acid to silver nitrate solution.
State two relevant observation of the following:
Ammonium hydroxide solution is added to copper (II) nitrate solution in small quantities and then in excess
The following table shows the tests a student performed on four different aqueous solutions which are X,Y,Z and W. Based on the observations provided, Identify the cation present
|
Chemical Test |
Observation | Conclusion |
| To Solution X, ammonium hydroxide is added in minium quantity first and then in excess | A dirty white precipitate is formed which dissolves in excess to form a clear solution | (i) |
| To Solution Y, ammonium hydroxide is added in minimum quantity first and then in excess | A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution | (ii) |
| To solution W, A small quantity of sodium hydroxide solution is added and then in excess | A white precipitate is formed which remains insoluble | (iii) |
| To a salt Z, calcium hydroxide solution is added and then heated | A pungent smelling gas turning moist red litmus paper blue is obtained | (iv) |
Identify the cation of the following case:
NaOH solution when added to solution (A) gives a reddish brown precipitate
The salt solution which does not react with ammonium hydroxide is ______.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
