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प्रश्न
Predict the major product, when 2-methyl-but-2-ene is converted into alcohol in the following method.
Hydroboration
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उत्तर
\[\begin{array}{cc}
\phantom{...............................................}\ce{CH3}\\
\phantom{............................................}|\\
\ce{6CH3 - C = CH - CH3 + B2H6 -> 2[(CH3)2 CH - CH -]_3 B}\\
|\phantom{..........................................}\\
\ce{\underset{(2-methyl-but-2-ene)}{CH3}}\phantom{.......................................}
\end{array}\]
\[\begin{array}{cc}
\phantom{..}\ce{CH3}\phantom{............................}\ce{CH3}\phantom{...}\ce{CH3}\phantom{...}\\
\phantom{.}|\phantom{................................}|\phantom{......}|\phantom{....}\\
\ce{[(CH3)2 CH - CH -]_3 B + 3H2O2 ->[OH^Θ] \underset{(3-methyl-butan-2-ol)}{3CH3 - CH - CH - OH} + H3BO3}
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{......}\\
|\phantom{........}\\
\ce{H3C - CH - CH - CH - CH2 - OH}\\
|\phantom{............}|\phantom{........}\\
\ce{Cl}\phantom{...........}\ce{CH3}\phantom{......}
\end{array}\]
