मराठी
महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Explain homoleptic and heteroleptic complexes.

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प्रश्न

Explain homoleptic and heteroleptic complexes.

स्पष्ट करा
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उत्तर

  1. Homoleptic complexes: The complexes in which metal ion is bound to only one type of ligands are called homoleptic complexes.
    e.g. In [Co(NH3)6]3+, only one type of ligand, NH3 surrounds the Co3+ ion.
  2. Heteroleptic complexes: The complexes in which metal ion is surrounded by more than one type of ligands are called heteroleptic complexes.
    e.g. In complex [Co(NH3)4Cl2]+, there are two types of ligands, NH3 and Cl attached to Co3+ ion.
  3. Double Salt: Double salts are ionic substances created by combining two distinct salt compounds. In aqueous media, double salts totally dissociate.
    eg. FeSO4 (NH4) 2SO4 · 6H2O (Mohr's salt).
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पाठ 9: Coordination Compounds - Short Answer Questions (Type-Ⅰ)

संबंधित प्रश्‍न

Choose the most correct option.

Which of the following complexes is chiral?

1. [Co(en)2Cl2]

2. [Pt(en)Cl2]

3. [Cr(C2O4)3]3-

4. [Co(NH3)4Cl2]


Answer the following in one or two sentences.

Is the complex [CoF6] cationic or anionic if the oxidation state of cobalt ion is +3?


Answer in brief.

Classify the following complexes as homoleptic and heteroleptic [Cu(NH3)4]SO4, [Cu(en)2(H2O)Cl]2⊕, [Fe(H2O)5 (NCS)]2⊕, tetraammine zinc (II) nitrate.


Answer the following question.

What are cationic, anionic, and neutral complexes? Give one example of each.


Explain the magnetic properties of [Ni(CN4)]2–.


Which of the following is CORRECT for [Co(NH3)5Br]Br2?


Identify the tetradentate ligand from the following.


Which statement from following is true for a complex hexaminecobalt (III) chloride?


Which from following complexes, the central metal ion does NOT obey BAN rule?

(Atomic number: Pt = 78, Cu = 29, Zn = 30, Fe = 26)


Which among the following complexes is a heteroleptic and cationic in nature?


Which among the following complexes is NOT a heteroleptic complex?


Which among the following compounds is cationic complex?


Identify cationic complex from the following.


Which coordinate complex from the following has a complex ion with positive charge?


Explain cationic, anionic and neutral sphere complexes w ith example.


The correct order of ligands in the spectrochemical series is ______.


Which among the following cations forms a least stable complex if the ligand is same?


What is the number of donor atoms in dimethylglyoximato ligand?


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