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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Consider the half reactions with standard potentials. i. AgA(aq)⊕+eA⊖⟶AgA(s)EA∘= 0.8V ii. IA2A(s)+2eA⊖⟶2IA⊖A(aq) EA∘= 0.53V iii. PbA2⊕A(aq)+2eA⊖⟶PbA(s) EA∘=−0.13V iv. FeA2⊕+2eA⊖⟶FeA(s) EA∘=−0.44V The - Chemistry

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प्रश्न

Consider the half reactions with standard potentials.

  1. \[\ce{Ag^{\oplus}_{ (aq)} + e^{\ominus} -> Ag_{(s)}E^\circ = 0.8 V}\] 
  2. \[\ce{I2_{(s)} + 2e^\ominus -> 2I^{\ominus}_{(aq)} E^\circ = 0.53V}\]
  3. \[\ce{Pb^{2\oplus}_{(aq)} + 2e^{\ominus} -> Pb_{(s)} E^\circ = -0.13 V}\]
  4. \[\ce{Fe^{2\oplus} + 2e^{\ominus} -> Fe_{(s)} E^\circ = -0.44 V}\]

The strongest oxidising  and reducing agents respectively are ______.

पर्याय

  • \[\ce{Ag and Fe^{2\oplus}}\]

  • \[\ce{Ag^{\oplus} and Fe}\]

  • \[\ce{Pb^{2\oplus} and I}\]

  • \[\ce{I2 and Fe^{2\oplus}}\]

MCQ
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उत्तर

The strongest oxidising  and reducing agents respectively are \[\ce{Ag^{\oplus} and Fe}\].

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Electrode Potential and Cell Potential
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पाठ 5: Electrochemistry - Exercises [पृष्ठ ११७]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 5 Electrochemistry
Exercises | Q 1.06 | पृष्ठ ११७

संबंधित प्रश्‍न

Choose the most correct option.

The standard potential of the cell in which the following reaction occurs:
H2 (g,1 atm) + Cu2+ (1M) → 2H+ (1M) + Cu(s),
`("E"_"Cu"^circ = 0.34 "V")` is


Answer the following in one or two sentences.

What is standard cell potential for the reaction

\[\ce{3Ni_{(s)} + 2Al^{3+} (1M) → 3Ni^{2+} (1M) + 2Al(s)}\], if `E_"Ni"^circ` = –0.25 V and  `"E"_("Al")^circ` = –1.66 V?


Answer the following in brief.

Construct a galvanic cell from the electrodes Co3+ | Co and Mn2+/Mn. \[\ce{E{^{\circ}_{Co}}}\] = 1.82 V, \[\ce{E{^{\circ}_{Mn}}}\] = –1.18 V. Calculate \[\ce{E{^{\circ}_{cell}}}\]


Calculate emf of the cell at 25°C.

Zn(s) | Zn2+ (0.08 M) || Cr3+ (0.1 M) | Cr(s)

`E_(Zn)^0` = −0.76 V,  `E_(Cr)^0` = −0.74 V


Answer the following:

Predict whether the following reaction would occur spontaneously under standard state condition.

`"Ca"_(("s")) + "Cd"_(("aq"))^(2+) -> "Ca"_(("aq"))^(2+) + "Cd"_(("s"))`


Calculate the voltage of the cell Sn(s) / Sn2+(0.02 M) // Ag+ (0.01 M) / Ag(s) at 25 °C.

Given: `"E"_"Sn"^circ` = - 0.136, `"E"_"Ag"^circ` = 0.800 V


Calculate `"E"_"cell"^circ` of the following galvanic cell:

Mg(s) / Mg2+(1 M) // Ag+ (1 M) / Ag(s) if `"E"_"Mg"^circ` = – 2.37 V and `"E"_"Ag"^circ` = 0.8 V. Write cell reactions involved in the above cell. Also mention if cell reaction is spontaneous or not.


The correct representation of Nernst's equation for half-cell reaction \[\ce{Cu^{2+} (aq) + e^- -> Cu^+(aq)}\] is ______.


Nernst equation for the following cell reaction at 298 K is:

\[\ce{Mg_{(s)} | Mg^{2+}_{( aq)} || Ag^+_{( aq)} | Ag_{(s)}}\]


Calculate E.M.F. of following cell at 298 K Zn(s) |ZnSO4 (0.01 M)| |CuSO4 (1.0 M)| Cu(s) if \[\ce{E^0_{cell}}\] = 2.0 V.


For the following cell, standard potential of copper electrode is 0.337 V and standard cell potential is 0.463 V.

\[\ce{Cu | Cu^{2+} (1 M) || Ag^+ (1 M)  Ag}\]

What is the standard potential of silver electrode?


What is the standard potential of cell, Ni | Ni2+ (1M) || Cu2+ (1 M) | Cu?

If E°Cu = 0.337 V and E°Ni = - 0.236 V.


The standard electrode potential of Zn and Ni are - 0.76 V and - 0.25 V respectively. If the reaction takes place in the cell constructed between these two electrodes is spontaneous. What is the standard emf of the cell?


The standard EMF for the cell reaction,
\[\ce{Zn + Cu^{2+} -> Zn^{2+} + Cu}\], 
is 1.10 V at 25°C. The EMF of the cell reaction, when 0.1 M Cu2+ and 0.1 M Zn2+ solutions are used at 25°C is:


Construct a cell from Ni2+ | Ni and Cu2+ | Cu Cu half cells. Write the cell reaction and calculate `E_("cell")^0`   
`(E_("Ni")^0 = - 0.236  V and E_("Cu")^0 = + 0.337  V)`


Define standard electrode potential.


The standard potential of the electrode Zn2+(0.02M) |Zn(s) is − 0.76 V. Calculate the electrode potential of the zinc electrode.


Calculate the emf of the following cell at 25°C.

Zn(s)|Zn2+(0.08 M) || Cu2+(0.l M) |Cu(s)

E0zn = − 0.76 V, E0cu = 0.36 V.


Write the value of `(2.303 RT)/F` in the Nernst equation?


Write the four applications of emf series.


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