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Are the enthalpies of atomisation of Zinc and Copper matched correctly? Justify your answer. Element Zinc Copper Enthalpy of atomisation/ kJmol−1 339 130 - Chemistry

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प्रश्न

Are the enthalpies of atomisation of Zinc and Copper matched correctly? Justify your answer.

Element Enthalpy of atomisation/kJ mol−1
Zinc 339
Copper 130
औचित्य
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उत्तर

No. The values are not matched correctly.

Explanation:

Zinc has a lower enthalpy of atomisation (~130 kJ mol−1) because its configuration [Ar]3d104s2 has no unpaired electrons, resulting in weaker metallic bonding.

Copper has a higher enthalpy of atomisation (~339 kJ mol−1) due to the presence of one unpaired electron in its 3d94s1 configuration, which leads to stronger metallic bonding.

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