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Actinoid contraction is greater from element to element than the lanthanoid contraction, why? - Chemistry

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प्रश्न

Actinoid contraction is greater from element to element than the lanthanoid contraction, why?

थोडक्यात उत्तर
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उत्तर

  1. Actinoid contraction is greater from element to element than lanthanoid contraction. The 5f orbitals in Actinoids have a very poorer shielding effect than 4f orbitals in lanthanoids.
  2. Thus, the effective nuclear charge experienced by electrons in valence shells in the case of actinoids is much more than that experienced by lanthanoids.
  3. In actinoids, electrons are shielded by 5d, 4f, 4d and 3d whereas in lanthanoids, electrons are shielded by 4d, 4f only.
  4. Hence, the size contraction in actinoids is greater as compared to that in lanthanoids.
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पाठ 4: Transition and Inner Transition Elements - Evaluation [पृष्ठ १२९]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
पाठ 4 Transition and Inner Transition Elements
Evaluation | Q 18. | पृष्ठ १२९
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