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Justify the position of lanthanides and actinides in the periodic table. - Chemistry

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प्रश्न

Justify the position of lanthanides and actinides in the periodic table.

थोडक्यात उत्तर
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उत्तर

Lanthanides:

1. The actual position of lanthanides in the periodic table is group number 3 and period number 6.

2. In the sixth period, the electrons are preferentially filled in the inner 4f sub shell.

3. The fourteen elements following lanthanum (Ce to Lu) show similar chemical properties.

4. Hence they are grouped together and placed at the bottom of the periodic table.

5. This position is justified as follows:

  • General electronic configuration: [Xe] 4f1-14 5d0-1 6S2
  • Common Oxidation state: +3
  • They have similar physical and chemical properties.

Actinides:

1. The actual position of actinides in the periodic table is group number 3 and period number 7.

2. In the seventh period, the electrons are preferentially filled in the inner 5f Sub shell.

3. The fourteen elements following actinides (Th to Lr) show similar chemical properties.

4. Hence they are grouped together and placed at the bottom of the periodic table.

5. This position is justified as follows:

  • General electronic configuration: [Rn] 5f2-14 6d0-2 7S2
  • Common oxidation state: +3
  • They have similar physical and chemical properties.
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पाठ 4: Transition and Inner Transition Elements - Evaluation [पृष्ठ १२८]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
पाठ 4 Transition and Inner Transition Elements
Evaluation | Q 4. | पृष्ठ १२८

संबंधित प्रश्‍न

Which one of the following statements related to lanthanons is incorrect?


Which of the following lanthanoid ions is diamagnetic?


The most common oxidation state of actinoids is ____________.


The actinoid elements which show the highest oxidation state of +7 are ____________.


What is lanthanoid contraction and what are the effects of lanthanoid contraction?


Actinoid contraction is greater from element to element than the lanthanoid contraction, why?


In the modern periodic table, elements are arranged in order of increasing atomic numbers which is related to the electronic configuration. Depending upon the type of orbitals receiving the last electron, the elements in the periodic table have been divided into four blocks, viz, s, p, d and f. The modern periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a new energy shell. In accordance with the Arfbau principle, the seven periods have 2, 8, 8, 18, 18, 32 and 32 elements respectively. The seventh period is still incomplete. To avoid the periodic table being too long, the two series of f-block elements, called lanthanoids and actinoids are placed at the bottom of the main body of the periodic table.

The elements with atomic numbers 35, 53 and 85 are all ______.


Illustrate by taking examples of transition elements and non-transition elements that oxidation states of elements are largely based on electronic configuration.


Electronic configuration, [Ne] 3s2 3p4 is for ______.


Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: Size of Bk3+ ion is less than Np3+ ion.

Reason R: The above is a consequence of the lanthanoid contraction.

In the light of the above statements, choose the correct answer from the options given below.


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