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प्रश्न
Account for the following:
Mn2+ is more stable than Fe2+ towards oxidation to +3 state.
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उत्तर
Electronic configuration of Mn2+ is [Ar]18 3d5 .
Electronic configuration of Fe2+ is [Ar]18 3d6 .
It is known that half-filled and fully-filled orbitals are more stable. Therefore, Mn in the +2 state has a stable d5 configuration. Therefore, Mn2+ shows resistance to oxidation to Mn3+. Also, Fe2+ has a 3d6 configuration and by losing one electron, its configuration changes to a more stable 3d5 configuration. Therefore, Fe2+ gets oxidised to Fe3+ easily.
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संबंधित प्रश्न
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Scandium (Z = 21) is a transition element but Zn (Z = 30) is not.
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| (i) | lowest enthalpy of atomisation | (p) | Sc |
| (ii) | shows maximum number of oxidation states | (q) | Mn |
| (iii) | transition metal that does not form coloured compounds |
(r) | Zn |
| (s) | Ti |
