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Calculate the packing efficiency for bcc lattice.
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In case of hcp structure, how are spheres in first, second and third layers arranged?
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A substance crystallizes in fcc structure. The unit cell edge length is 367.8 pm. Calculate the molar mass of the substance if its density is 21.5 g/cm3.
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The following solution/solvent has maximum vapour pressure _______.
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According to Raoult’s law, relative lowering of vapour pressure of solution containing dissolved nonvolatile solute _______.
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Write the expression for relative lowering of vapour pressure.
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The vapour pressure of a pure liquid is 0.043 bar at a certain temperature. When a nonvolatile solute is dissolved into it, the vapour pressure of the solution is found to be 0.041 bar. What is the relative lowering of vapour pressure?
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For a very dilute solution, the osmotic pressure is given by π = n2RT/V where V is the volume in L containing n2 moles of nonvolatile solute. Establish the equation for molar mass of solute.
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Give two points to explain why vapour pressure of solvent is lowered by dissolving nonvolatile solute into it.
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NH4F is a salt of weak acid HF (Ka = 7.2 × 10–4) and weak base NH4OH (Kb = 1.8 × 10–5), the solution of NH4F will be ______.
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Give any one example of salt derived from weak acid and weak base.
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Define Hydrolysis of salt.
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Calculate `"E"_"cell"^0` for galvanic cell with electrodes Co/Co3+// Mn2+/Mn.
`"E"_"Mn"^0` = - 1.18 V, `"E"_"Co"^0` = 1.82 V.
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Give the chemical composition present in the salt bridge.
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What are the functions of a salt bridge in a galvanic cell?
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Represent the galvanic cell from following overall cell reaction:
3Ni(s) + 2Al3+ (1 M) → 3Ni2+(1 M) + 2Al(s)
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Calculate standard cell potential of following galvanic cell:
Zn/Zn2+(1 M) // Pb2+(1 M)/Pb. If `"E"_"Pb"^0` = 0.126 V and `"E"_"Zn"^0` = –0.763 V
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Calculate the voltage of the cell Sn(s) / Sn2+(0.02 M) // Ag+ (0.01 M) / Ag(s) at 25 °C.
Given: `"E"_"Sn"^circ` = - 0.136, `"E"_"Ag"^circ` = 0.800 V
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Calculate `"E"_"cell"^circ` of the following galvanic cell:
Mg(s) / Mg2+(1 M) // Ag+ (1 M) / Ag(s) if `"E"_"Mg"^circ` = – 2.37 V and `"E"_"Ag"^circ` = 0.8 V. Write cell reactions involved in the above cell. Also mention if cell reaction is spontaneous or not.
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