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HSC Science (Computer Science) १२ वीं कक्षा - Maharashtra State Board Question Bank Solutions for Chemistry

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Chemistry
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The rate constant for the first-order decomposition of H2O2 is given by the following equation:

`logk=14.2-(1.0xx10^4)/TK`

Calculate Ea for this reaction and rate constant k if its half-life period be 200 minutes.

(Given: R = 8.314 JK–1 mol–1)

[5] Chemical Kinetics
Chapter: [5] Chemical Kinetics
Concept: undefined >> undefined

The rate constant of a first order reaction increases from 2 × 10−2 to 4 × 10−2 when the temperature changes from 300 K to 310 K. Calculate the energy of activation (Ea).

(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

[5] Chemical Kinetics
Chapter: [5] Chemical Kinetics
Concept: undefined >> undefined

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What type of battery is mercury cell? Why is it more advantageous than dry cell?

[4] Electrochemistry
Chapter: [4] Electrochemistry
Concept: undefined >> undefined

An element with density 2.8 g cm–3 forms a f.c.c. unit cell with edge length 4 x 10–8 cm. Calculate the molar mass of the element.

(Given : NA = 6.022 x 1023 mol –1)

[1] Solid State
Chapter: [1] Solid State
Concept: undefined >> undefined

Name the type of cell which was used in Apollo space programme for providing electrical power.

[4] Electrochemistry
Chapter: [4] Electrochemistry
Concept: undefined >> undefined

Define terms: Fuel cell

[4] Electrochemistry
Chapter: [4] Electrochemistry
Concept: undefined >> undefined

Define the following terms: Secondary batteries

[4] Electrochemistry
Chapter: [4] Electrochemistry
Concept: undefined >> undefined

Which of the following pairs is an intensive property?

(A) Density, viscosity

(B) Surface tension, mass

(C) Viscosity, internal energy

(D) Heat capacity, volume

[3] Chemical Thermodynamics and Energetic
Chapter: [3] Chemical Thermodynamics and Energetic
Concept: undefined >> undefined

In the Arrhenius equation for a first order reaction, the values of ‘A’ of ‘Ea’ are 4 × 1013 sec−1 and 98.6 kJ mol1 respectively. At what temperature will its half life period be 10 minutes?

[R = 8.314 J K1 mol1]

[5] Chemical Kinetics
Chapter: [5] Chemical Kinetics
Concept: undefined >> undefined

Which of the following is a basic oxide?

(A) SiO2

(B) P4O10

(C) MgO

(D) Al2O3

[7.01] Group 15 Elements
Chapter: [7.01] Group 15 Elements
Concept: undefined >> undefined

55 L atm of work is obtained when 1.0 mole of an ideal gas is compressed isothermally from
a volume of 28.5 L to 18.5 L, the constant external pressure is

(A) 5.05 atm

(B) 5.5 atm

(C) 0.05 atm

(D) 0.55 atm

[3] Chemical Thermodynamics and Energetic
Chapter: [3] Chemical Thermodynamics and Energetic
Concept: undefined >> undefined

A metal crystallises into two cubic faces namely face centered (FCC) and body centered (BCC), whose unit cell edge lengths are 3.5 Å and 3.0 Å respectively. Find the ratio of the densities of FCC and BCC.

[1] Solid State
Chapter: [1] Solid State
Concept: undefined >> undefined

When phenol is heated with conc. HNO3 in presence of conc. H2SO4 it yields _______.

(A) o-nitrophenol

(B) p-nitrophenol

(C) 2,4,6-trinitrophenol

(D) m-nitrophenol

[11.02] Phenols
Chapter: [11.02] Phenols
Concept: undefined >> undefined

Draw the structure of the chromate ion.

[8.01] D-block Elements
Chapter: [8.01] D-block Elements
Concept: undefined >> undefined

Which of the following compounds is used as a semipermeable membrane?

(a) Potassium ferrocyanide

(b) Potassium argentocyanide

(c) Sodium meta aluminate

(d) Copper ferrocyanide

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
Concept: undefined >> undefined

The rate constant of a first order reaction are 0.58 S-1 at 313 K and 0.045 S-1 at 293 K. What is the energy of activation for the reaction?

[5] Chemical Kinetics
Chapter: [5] Chemical Kinetics
Concept: undefined >> undefined

Predict the co-ordination No. of cs+ ion if `r_(Cs)^+` = 1.69Å and `r_(Cl)^-` = 1.81Å.

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
Concept: undefined >> undefined

IUPAC name of the following compound is

(a) 3 - Bromo- 3, 4- dimethylheptane

(b) 3, 4- dimethyl - 3- bromoheptane

(c) 5- Bromo- 4, 5- dimethylheptane

(d) 4, 5- dimethyl- 5- bromoheptane

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
Concept: undefined >> undefined

Write IUPAC names of the following compounds

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
Concept: undefined >> undefined

Write IUPAC names of the following compounds:

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
Concept: undefined >> undefined
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