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HSC Science (Computer Science) १२ वीं कक्षा - Maharashtra State Board Question Bank Solutions for Chemistry

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Chemistry
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Write the mathematical equation of the first law of thermodynamics for an isochoric process.

[3] Chemical Thermodynamics and Energetic
Chapter: [3] Chemical Thermodynamics and Energetic
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Draw a neat and well labelled diagram of primary reference electrode.

[4] Electrochemistry
Chapter: [4] Electrochemistry
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How is 1-nitropropane prepared from suitable oxime?

[12.02] Carboxylic Acids
Chapter: [12.02] Carboxylic Acids
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How are  2 - nitropropane prepared from suitable oxime?

[12.02] Carboxylic Acids
Chapter: [12.02] Carboxylic Acids
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Write the reaction for the preparation of Nylon-6.

[15] Polymers
Chapter: [15] Polymers
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Write the reactions involved in dehydration of 1°, 2° and 3° alcohols.

[11.01] Alcohols
Chapter: [11.01] Alcohols
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How are 1 - nitropropane, 2-nitropropane and 2-methyl 2- nitropropane are distinguished from each other using nitrous acid?

[13.01] Amines
Chapter: [13.01] Amines
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Phenelzine is used as an

(a)  analgesic                      

(b) antiseptic

(c) antipyretic

(d) antidepressant

[11.02] Phenols
Chapter: [11.02] Phenols
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The integrated rate equation for first order reaction is A → products

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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Derive the relation between half life and rate constant for a first order reaction

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer 

Element

Al(s)

Cu(s)

Cl(aq)

Ni(s)

 

Eo

-1.66V

0.34V

1.36V

-0.26V

 

[4] Electrochemistry
Chapter: [4] Electrochemistry
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1.0 x10-3Kg of urea when dissolved in 0.0985 Kg of a solvent, decreases freezing point of the solvent by 0.211 k. 1.6x10 Kg of another non-electrolyte solute when dissolved in 0.086 Kg of the same solvent depresses the freezing point by 0.34 K. Calculate the molar mass of the another solute. (Given molar mass of urea = 60)

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
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Write one statement of first law of thermodyamics and its mathematical expression.

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
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Write one statement of first law of thermodyamics and its mathematical expression.

[3] Chemical Thermodynamics and Energetic
Chapter: [3] Chemical Thermodynamics and Energetic
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Calculate Ecell and ΔG for the following at 28°C :

Mg(s) + Sn2+( 0.04M ) → Mg2+( 0.06M ) + Sn(s)

cell = 2.23V. Is the reaction spontaneous ?

[4] Electrochemistry
Chapter: [4] Electrochemistry
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Identify the product ‘D’ in the following sequence of reactions:

\[\ce{H3C - CH2 - CH2 - Cl \underset{KOH}{\overset{Alc}{->}} 'B' \overset{HBr}{->} 'C' \underset{Elther}{\overset{Na}{->}}'D'}\]

[10.01] Haloalkanes
Chapter: [10.01] Haloalkanes
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Primary and secondary nitroalcanes containing α - H atom show property of -

  1. chain isomerism
  2. tautomerism
  3. optical isomerism
  4. geometrical isomerism
[13.01] Amines
Chapter: [13.01] Amines
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Write mechanism of Aldol addition reaction.

[12.01] Aldehydes and Ketones
Chapter: [12.01] Aldehydes and Ketones
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The hybridisation of phosphorus in phosphorus pentachloride is _______.

(A) dsp3

(B) sp3 d

(C) d2 sp3

(D) sp3 d2

[7.01] Group 15 Elements
Chapter: [7.01] Group 15 Elements
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The rate constant for a first order reaction is 100 s–1. The time required for completion of 50% of reaction is _______.

(A) 0.0693 milliseconds

(B) 0.693 milliseconds

(C) 6.93 milliseconds

(D) 69.3 milliseconds

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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