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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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On the basis of crystal field theory, write the electronic configuration for d4 ion if ∆0 < P.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Amino acids show amphoteric behaviour. Why?

[10] Biomolecules
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Define the following term

Schottky defect

[1] Solid State
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What type of battery is mercury cell? Why is it more advantageous than dry cell?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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What type of non-stoichiometric point defect is responsible for the pink colour of LiCl ?

[1] Solid State
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What type of stoichiometric defect is shown by NaCl ?

[1] Solid State
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Name the type of cell which was used in Apollo space programme for providing electrical power.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Write the chemical equations to illustrate the following name reaction: 

Cannizzaro’s reaction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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Which stoichiometric defect does not change the density of the crystal?

[1] Solid State
Chapter: [1] Solid State
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Define terms: Fuel cell

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Which stoichiometric defect decreases the density of the crystal?

[1] Solid State
Chapter: [1] Solid State
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Define the following terms: Secondary batteries

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Define the following term:

Essential amino acids

[10] Biomolecules
Chapter: [10] Biomolecules
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What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?

[1] Solid State
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What type of stoichiometric defect is shown by:

(i) ZnS 

(ii) AgBr

[1] Solid State
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Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water.

[1] Solutions
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In the button cells widely used in watches and other devices, the following reaction takes place:

\[\ce{Zn_{(s)} + Ag2O_{(s)} + H2O_{(l)} -> Zn{^{2+}_{(aq)}} + 2Ag_{(s)} + 2OH^-_{ (aq)}}\]

Determine ΔrG° and E° for the reaction.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Comment on the statement that “colloid is not a substance but a state of substance”.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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The hexaquo manganese (II) ion contains five unpaired electrons, while the hexacyanoion contains only one unpaired electron. Explain using Crystal Field Theory.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Draw figure to show the splitting of d orbitals in an octahedral crystal field.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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