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Account for the following:
o-nitrophenol is more steam volatile than p-nitrophenol.
Concept: Chemical Reactions of Alcohols and Phenols >> Reactions Involving Cleavage of O-H Bond
Give simple chemical test to distinguish between Ethanol and Phenol.
Concept: Commercially Importance Alcohols
Give reasons for the following:
Sulphur in vapour state shows paramagnetic behaviour.
Concept: Group 16 Elements - The Oxygen Family >> Sulphur - Allotropic Forms
Give reasons for the following:
Ozone is thermodynamically less stable than oxygen.
Concept: Group 16 Elements - The Oxygen Family >> Ozone
Write the name of gas released when Cu is added to
dilute HNO3
Concept: Group 15 Elements - The Nitrogen Family >> Nitric Acid
Write the name of gas released when Cu is added to
conc. HNO3
Concept: Group 15 Elements - The Nitrogen Family >> Nitric Acid
Convert the following:
Propanenitrile to ethanol.
Concept: Commercially Importance Alcohols
What happens when reactions:
N-ethylethanamine reacts with benzenesulphonyl chloride.
Concept: Methods of Preparation of Phenols
What happens when reactions:
Benzylchloride is treated with ammonia followed by the reaction with Chloromethane.
Concept: Group 15 Elements - The Nitrogen Family >> Ammonia
The major product of acid catalysed dehydration of 1-methylcyclohexanol is ______.
Concept: Methods of Preparation of Alcohols
Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): An ether is more volatile than an alcohol of comparable molecular mass
Reason (R): Ethers are polar in nature.
Select the most appropriate answer from the options given below:
Concept: Physical Properties of Ethers
Name the suitable alcohol and reagent, from which 2-Chloro-2-methyl propane can be prepared.
Concept: Preparation of Ethers
Write the equations for the following reaction:
Tert butyl chloride is treated with sodium ethoxide.
Concept: Preparation of Ethers
Arrange the following in the increasing order of their property indicated:
4-Nitrobenzoic acid, benzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxy benzoic acid (Acid strength)
Concept: Chemical Reactions of Alcohols and Phenols >> Reactions Involving Cleavage of O-H Bond
Which of the following reactions are feasible?
Concept: Preparation of Ethers
Write the equation for the following:
Reaction of chlorobenzene with CH3Cl/anhyd. AlCl3.
Concept: Chemical Reaction of Ethers - Electrophilic Substitution
Which of the following observation is shown by 2-phenyl ethanol with Lucas Reagent?
Concept: Chemical Reactions of Alcohols and Phenols >> Reactions Involving Cleavage of Carbon–Oxygen (C–O) Bond in Alcohols
Anisole undergoes bromination with bromine in ethanoic acid even in the absence of iron (III) bromide catalyst.
Concept: Chemical Reaction of Ethers - Electrophilic Substitution
Write the name of the reaction, structure and IUPAC name of the product formed when:
\[\ce{CH3CH2CH(CH3)CH(CH3) ONa}\] reacts with \[\ce{C2H5Br}\]
Concept: Preparation of Ethers
Write the structure of 3-methyl butanal
Concept: Nomenclature of Aldehydes and Ketones
