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Write the product in the following reaction - Chemistry

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प्रश्न

Write the product in the following reaction

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उत्तर

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2015-2016 (March) All India Set 2 C

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संबंधित प्रश्न

Write the product in the following reaction:


The oxidation of toluene to benzoic acid can be stopped at the aldehyde stage to give benzaldehyde. The reagent used for the purpose is one of the following.


Aldehydes are prepared by reducing nitriles to corresponding imines with stannous chloride in the presence of hydrochloric acid. This reaction is called:


Ethylbenzene is generally prepared by acetylation of benzene followed by reduction and not by direct alkylation. Think of a possible reason.


Match the example given in Column I with the name of the reaction in Column II.

  Column I
(Example)
  Column II
(Reaction)
(i) \[\begin{array}{cc}
\phantom{...}\ce{O}\phantom{..............................}\ce{O}\phantom{}\\
\phantom{...}||\phantom{..............................}||\phantom{}\\
\ce{CH3 - C - Cl + H2 ->[Pd - C/BasO4] CH3 - C - H}
\end{array}\]
(a) Friedel Crafts acylation
(ii) (b) HVZ reaction
(iii) (c) Aldol condensation
(iv) \[\begin{array}{cc}
\ce{R - CH2 - COOH ->[Br/Red P] R - CH - COOH}\\
\phantom{.....................}|\\
\phantom{.......................}\ce{Br}
\end{array}\]
(d) Cannizaro’s reaction
(v) \[\ce{CH3 - CN ->[(i) SnCl2/HCl][(ii) H2O/H+] CH3CHO}\] (e) Rosenmund’s reductio
(vi) \[\ce{2CH3CHO ->[NaOH] CH3 - CH = CHCHO}\] (f) Stephen’s reaction

An aromatic compound ‘A’ (Molecular formula \[\ce{C8H8O}\]) gives positive 2, 4-DNP test. It gives a yellow precipitate of compound ‘B’ on treatment with iodine and sodium hydroxide solution. Compound ‘A’ does not give Tollen’s or Fehling’s test. On drastic oxidation with potassium permanganate it forms a carboxylic acid ‘C’ (Molecular formula \[\ce{C7H6O2}\]), which is also formed along with the yellow compound in the above reaction. Identify A, B and C and write all the reactions involved.


What is the name of the given reaction of preparation of aldehyde?

\[\ce{C3COCl ->[H2][Pd/BaSO4] CH3CHO + HCl}\]


Aldehydes are the first oxidation products of ______.


Predict the reagent for carrying out the following transformations:

Benzoyl chloride to Benzaldehyde


Write the name of the reaction, structure and IUPAC name of the product formed when:

CH3CH2CN reacts with stannous chloride in the presence of hydrochloric acid, followed by hydrolysis.


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