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प्रश्न
Write the mechanism of free radical polymerization of ethene.
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उत्तर
Free radical mechanism for polymerisation of ethene
Chain-initiating step
Chain-propagating step
Chain-terminating step
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संबंधित प्रश्न
How are polythene and neoprene prepared?
Write the molecular formula and structural formula of BHA and BHT.
Out of chain growth polymerisation and step growth polymerisation, in which type will you place the following.
Why should the monomers used in addition polymerisation through free radical pathway be very pure?
Match the polymer of column I with correct monomer of column II.
| Column I | Column II |
| (i) High density polythene | (a) Isoprene |
| (ii) Neoprene | (b) Tetrafluoroethene |
| (iii) Natural rubber | (c) Chloroprene |
| (iv) Teflon | (d) Acrylonitrile |
| (v) Acrilan | (e) Ethene |
Match the polymers given in Column I with the preferred mode of polymerisation followed by their monomers.
| Column I | Column II |
| (i) Nylon-6,6 | (a) Free radical polymerisation |
| (ii) PVC | (b) Ziegler-Natta polymerisation or coordination polymerisation |
| (iii) HDP | (c) Anionic polymerisation |
| (d) Condensation polymerisation |
Assertion: Olefinic monomers undergo addition polymerisation.
Reason: Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.
By which reaction ethene is obtained from ethyne?
The Ziegler Natta catalyst are
\[\ce{X + C + Cl2 ->[High temperature][of about 1000 K] Y + CO}\];
\[\ce{Y + 2H2O -> Z + 2HCl}\]
Compound Y is found in polymeric chain structure and is an electron-deficient Molecule. Y must be:
