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प्रश्न
What is the significance of Henry’s Law constant KH?
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उत्तर
Henry's law is expressed mathematically as,
p = KH x
(where, p is the partial pressure of the gas in vapour phase and x is the mole fraction of the gas in solution)
Thus it is significant from above equation that,
"higher the value of Henry’s law constant KH, the lower is the solubility of the gas in the liquid".
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संबंधित प्रश्न
Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of KH (Henry’s constant) and why
Why do gases always tend to be less soluble in liquids as the temperature is raised?
Henry’s law constant for CO2 in water is 1.67 × 108 Pa at 298 K. Calculate the quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
The partial pressure of ethane over a solution containing 6.56 × 10−3 g of ethane is 1 bar. If the solution contains 5.00 × 10−2 g of ethane, then what shall be the partial pressure of the gas?
Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.
Which mixture is used for respiration by deep sea divers?
(A) He + O2
(B) Ne + O2
(C) Ar + O2
(D) Kr + O2
How does solubility of a gas in water varies with the temperature?
Give reasons for the following :
Aquatic animals are more comfortable in the cold water than in warm water.
The solubility product of PbCl2 at 298K is 1.7 × 10-5. Calculate the solubility of PbCl2 in g/lit. at 298K.
Atomic Weights: [Pb = 207 and Cl = 35.5]
Which law shows relation between pressure and solubility of a gas in solvent?
The value of Henry's constant KH is ______.
Which of the following factor(s) affect the solubility of a gaseous solute in the fixed volume of liquid solvent?
(a) nature of solute
(b) temperature
(c) pressure
(i) (a) and (c) at constant T
(ii) (a) and (b) at constant P
(iii) (b) and (c) only
(iv) (c) only
KH value for \[\ce{Ar(g)}\], \[\ce{CO2(g)}\], \[\ce{HCHO (g)}\] and \[\ce{CH4(g)}\] are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively. Arrange these gases in the order of their increasing solubility.
Explain the following phenomena with the help of Henry’s law.
Feeling of weakness and discomfort in breathing at high altitude.
State Henry’s law and explain why are the tanks used by scuba divers filled with air diluted with helium (11.7% helium, 56.2% nitrogen and 32.1% oxygen)?
Henry's constant (in k bar) for four gases α, β, γ and δ in water at 298 K is given below:
| α | β | γ | δ | |
| KH | 50 | 2 | 2 × 10-5 | 0.5 |
(density of water = 103 kg m-3 at 298 K)
This table implies that:
In which of the following solvents, the \[\ce{C4H8NH3+X–}\] is soluble?
