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What is the role of adsorption in heterogenous catalysis? - Chemistry

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प्रश्न

What is the role of adsorption in heterogenous catalysis?

दीर्घउत्तर
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उत्तर

The role of heterogeneous catalysts can be explained in terms of adsorption of reactants on the surface of the catalyst.

The adsorption helps the reaction in the following ways:

(i) Adsorption increases the concentration of reactants on the surface of the catalyst. Due to increased concentration of the reactants, the reactions proceed rapidly.

(ii) Adsorbed molecules get dissociated to form active species like free radicals which react faster than molecules.

(iii) The adsorbed molecules are not free to move about and, therefore, they collide with other molecules on the surface.

(iv) The heat of adsorption evolved acts as energy of activation for the reaction (chemisorption).

Example: Adsorption of molecules of the reactant at the active site.

Occurrence of chemical reaction on the surface of catalyst

Desorption of product molecules
Example:

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अध्याय 5: Surface Chemistry - Exercises [पृष्ठ ७३]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 5 Surface Chemistry
Exercises | Q 78 | पृष्ठ ७३

संबंधित प्रश्न

Differentiate between adsorbtion and absorption.


What are the factors which influence the adsorption of a gas on a solid?


Write one similarity between Physisorption and Chemisorption


Give reasons for the following observations :

 Powdered substances are more effective  adsorbents.


How does chemisorption vary with temperature?


How does chemisorption vary with temperature?


Answer in one sentence:

Name type of adsorption in which vander Waals focres are present.


Answer in one sentence:

Name type of adsorption in which the compound is formed.


Which of the following compounds is formed when tungsten adsorbs oxygen gas?


Adsorption increases when ____________.


Which among the following is a property of physisorption?


Powdered substances are more effective adsorbents than their crystalline forms because ____________.


The extent of adsorption increases with the ____________.


The physical adsorption is due to ____________.


Which of the following is not a favourable condition for physical adsorption?


Why is it important to have clean surface in surface studies?


Why is chemisorption referred to as activated adsorption?


What is the role of diffusion in heterogenous catalysis?


Write three differences between physisorption and chemisorption.


Assertion A : Activated charcoal adsorbs SO2 more efficiently than CH4.

Reason R : Gases with lower critical temperatures are readily adsorbed by activated charcoal.
In light of the above statements, choose the correct answer from the options given below.


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