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The standard potential of the cell in the following reaction is ______. CdA(s)+CuA(1M)2+⟶CdA(1M)2++CuA(s) ECdECu(ECd∘=-0.403V,ECu∘=0.334V) - Chemistry

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प्रश्न

The standard potential of the cell in the following reaction is ______.

\[\ce{Cd_{(s)} + Cu^{2+}_{(1M)} -> Cd^{2+}_{(1M)} + Cu_{(s)}}\]

`("E"_("Cd")^circ = - 0.403V, "E"_("Cu")^circ = 0.334V)`

विकल्प

  • – 0.737 V

  • 0.737 V

  • – 0.069 V

  • 0.069 V

MCQ
रिक्त स्थान भरें
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उत्तर

The standard potential of the cell in the following reaction is 0.737 V.

Explanation:

`"E"_"cell"^circ = "E"_"RHE"^circ - "E"_"LHE"^circ`

= 0.334 – (– 0.403 V)

= 0.737 V

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Electrode Potential and Cell Potential
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
2021-2022 (March) Set 1

संबंधित प्रश्न

Choose the most correct option.

The standard potential of the cell in which the following reaction occurs:
H2 (g,1 atm) + Cu2+ (1M) → 2H+ (1M) + Cu(s),
`("E"_"Cu"^circ = 0.34 "V")` is


Consider the half reactions with standard potentials.

  1. \[\ce{Ag^{\oplus}_{ (aq)} + e^{\ominus} -> Ag_{(s)}E^\circ = 0.8 V}\] 
  2. \[\ce{I2_{(s)} + 2e^\ominus -> 2I^{\ominus}_{(aq)} E^\circ = 0.53V}\]
  3. \[\ce{Pb^{2\oplus}_{(aq)} + 2e^{\ominus} -> Pb_{(s)} E^\circ = -0.13 V}\]
  4. \[\ce{Fe^{2\oplus} + 2e^{\ominus} -> Fe_{(s)} E^\circ = -0.44 V}\]

The strongest oxidising  and reducing agents respectively are ______.


Answer the following in one or two sentences.

What is standard cell potential for the reaction

\[\ce{3Ni_{(s)} + 2Al^{3+} (1M) → 3Ni^{2+} (1M) + 2Al(s)}\], if `E_"Ni"^circ` = –0.25 V and  `"E"_("Al")^circ` = –1.66 V?


Answer the following in brief.

Construct a galvanic cell from the electrodes Co3+ | Co and Mn2+/Mn. \[\ce{E{^{\circ}_{Co}}}\] = 1.82 V, \[\ce{E{^{\circ}_{Mn}}}\] = –1.18 V. Calculate \[\ce{E{^{\circ}_{cell}}}\]


Calculate emf of the cell at 25°C.

Zn(s) | Zn2+ (0.08 M) || Cr3+ (0.1 M) | Cr(s)

`E_(Zn)^0` = −0.76 V,  `E_(Cr)^0` = −0.74 V


Answer the following:

Predict whether the following reaction would occur spontaneously under standard state condition.

`"Ca"_(("s")) + "Cd"_(("aq"))^(2+) -> "Ca"_(("aq"))^(2+) + "Cd"_(("s"))`


Calculate the voltage of the cell Sn(s) / Sn2+(0.02 M) // Ag+ (0.01 M) / Ag(s) at 25 °C.

Given: `"E"_"Sn"^circ` = - 0.136, `"E"_"Ag"^circ` = 0.800 V


Calculate `"E"_"cell"^circ` of the following galvanic cell:

Mg(s) / Mg2+(1 M) // Ag+ (1 M) / Ag(s) if `"E"_"Mg"^circ` = – 2.37 V and `"E"_"Ag"^circ` = 0.8 V. Write cell reactions involved in the above cell. Also mention if cell reaction is spontaneous or not.


Standard reduction electrode potentials of three metals A, B and C are +0.5 V, −3.0 V and −1.2 V respectively. The reducing power of these metals is ______.


The correct representation of Nernst's equation for half-cell reaction \[\ce{Cu^{2+} (aq) + e^- -> Cu^+(aq)}\] is ______.


Nernst equation for the following cell reaction at 298 K is:

\[\ce{Mg_{(s)} | Mg^{2+}_{( aq)} || Ag^+_{( aq)} | Ag_{(s)}}\]


Calculate E.M.F. of following cell at 298 K Zn(s) |ZnSO4 (0.01 M)| |CuSO4 (1.0 M)| Cu(s) if \[\ce{E^0_{cell}}\] = 2.0 V.


Calculate \[\ce{E^0_{cell}}\] for the following cell.

\[\ce{Cr_{(s)} | Cr^{3+}_{( aq)} || Fe^{2+}){( aq)} | Fe_{(s)}}\]

Given: `"E"_("Cr"^(3+)//"Cr")^0` = −0.74 V,

`"E"_("Fe"^(2+)//"Fe")^0` = −0.44 V


The reduction potential of a half-cell consisting of nickel electrode in 0.1 M NiSO4 solution at 25°C is ____________.

(E0 = −0.257 V)


What is the standard emf of the following cell?

\[\ce{Ni_{(s)} | Ni^{2+}_{( aq)} || Au^{3+}_{( aq)} | Au_{(s)}}\]

if \[\ce{E^0_{Ni}}\] = −0.25 V, \[\ce{E^0_{Au}}\] = 1.50 V.


What is the standard potential of cell, Ni | Ni2+ (1M) || Cu2+ (1 M) | Cu?

If E°Cu = 0.337 V and E°Ni = - 0.236 V.


The tendency of an electrode to lose electrons is known as ______


Define standard electrode potential.


The standard potential of the electrode Zn2+(0.02M) |Zn(s) is − 0.76 V. Calculate the electrode potential of the zinc electrode.


Calculate the emf of the following cell at 25°C.

Zn(s)|Zn2+(0.08 M) || Cu2+(0.l M) |Cu(s)

E0zn = − 0.76 V, E0cu = 0.36 V.


Write the value of `(2.303 RT)/F` in the Nernst equation?


Write the four applications of emf series.


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