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प्रश्न
How would you account for the following:
Actinoid contraction is greater than lanthanoid contraction.
Actinoid contraction is greater from element to element than lanthanoid contraction. Why?
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उत्तर
In actinoids, 5 f-orbitals are filled. These 5 f-orbitals have a poorer shielding effect than 4 f-orbitals (in lanthanoids). Thus, the effective nuclear charge experienced by electrons in valence shells in the case of actinoids is much more than that experienced by electrons in valence shells in the case of lanthanoids. Hence, the size contraction in actinoids is greater than that in lanthanoids.
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संबंधित प्रश्न
How would you account for the following:
The chemistry of actinoids is more complicated as compared to lanthanoids.
Give a reason for the following:
Actinoids show irregularities in their electronic configurations.
With reference to structural variability and chemical reactivity, write the differences between lanthanoids and actinoids
Compare the chemistry of the actinoids with that of lanthanoids with reference to electronic configuration
Compare the chemistry of the actinoids with that of lanthanoids with reference to oxidation states
Compare the chemistry of the actinoids with that of lanthanoids with reference to chemical reactivity.
Write four points of distinction between Lanthanoids and Actinoids.
Write one similarity and one difference between the chemistry of lanthanoid and actinoid elements.
How would you account the following :
Highest fluoride of Mn is MnF4 whereas the highest oxide is Mn2O7.
How do you prepare:
Actinoid elements show wide range of oxidation states.
Give reasons for the following:
The chemistry of actinoids elements is not so smooth as that of the lanthanoids.
Which of the following actinoids exhibits only + 3 oxidation state?
The highest oxidation state in plutonium (At. no. = 94) is ______.
Which among the following elements is radioactive?
Which of the following oxidation state is common for all lanthanoids?
Which of the following actinoids show oxidation states upto +7?
(i) Am
(ii) Pu
(iii) U
(iv) Np
Assertion: Actinoids form relatively less stable complexes as compared to lanthanoids.
Reason: Actinoids can utilise their 5f orbitals along with 6d orbitals in bonding but lanthanoids do not use their 4f orbital for bonding.
What are actinoids? Give their general electronic configuration.
