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Give a reason for the sigma (σ) bond is stronger than the Pi (π) bond. - Chemistry

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प्रश्न

Give a reason for the sigma (σ) bond is stronger than the Pi (π) bond.

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उत्तर

  1. The strength of the bond depends on the extent of overlap of the orbitals. Greater the overlap, the stronger is the bond.
  2. A sigma bond is formed by the coaxial overlap of the atomic orbitals which are oriented along the internuclear axis, hence the extent of overlap is maximum.
  3. A pi bond is formed by the lateral overlap of the atomic orbitals which are oriented perpendicular to the internuclear axis, hence the extent of orbital overlapping in a sidewise manner is less.
    Hence, the sigma (σ) bond is stronger than the Pi (π) bond.
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अध्याय 5: Chemical Bonding - Exercises [पृष्ठ ७९]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
अध्याय 5 Chemical Bonding
Exercises | Q 3. (H)(a) | पृष्ठ ७९

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