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प्रश्न
Discuss the effect of temperature on the adsorption of gases on solids.
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उत्तर
Adsorption is generally exothermic; hence, increasing temperature decreases adsorption. In physical adsorption, a rise in temperature weakens van der Waals forces, lowering adsorption. For chemical adsorption, it first increases with temperature due to activation energy requirements, then decreases at higher temperatures as desorption dominates. Thus, the effect of temperature depends on the type of adsorption.
संबंधित प्रश्न
Write the differences between physisorption and chemisorption with respect to the following:
(i) Specificity
(ii) Temperature dependence
(iii) Reversibility and
(iv) Enthalpy change
Differentiate between adsorbtion and absorption.
Why are powdered substances more effective adsorbents than their crystalline forms?
What are the factors which influence the adsorption of a gas on a solid?
Write one similarity between Physisorption and Chemisorption
How does chemisorption vary with temperature?
How does chemisorption vary with temperature?
Adsorption increases when ____________.
Which among the following is true for chemisorption?
In physisorption, adsorption is generally ____________.
Chromatography is based on the principle of ____________.
The extent of adsorption increases with the ____________.
The physical adsorption is due to ____________.
Which of the following is not a favourable condition for physical adsorption?
In physisorption adsorbent does not show specificity for any particular gas because ______.
What is the role of diffusion in heterogenous catalysis?
Assertion: Detergents with low CMC are more economical to use.
Reason: Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.
What is the role of adsorption in heterogenous catalysis?
