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प्रश्न
Discuss the effect of temperature on the adsorption of gases on solids.
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उत्तर
Adsorption is generally exothermic; hence, increasing temperature decreases adsorption. In physical adsorption, a rise in temperature weakens van der Waals forces, lowering adsorption. For chemical adsorption, it first increases with temperature due to activation energy requirements, then decreases at higher temperatures as desorption dominates. Thus, the effect of temperature depends on the type of adsorption.
संबंधित प्रश्न
Give reasons for the following observations:
Physisorption decreases with increase in temperature.
What is the effect of temperature on chemisorption ?
Why is adsorption always exothermic?
Distinguish between the meaning of the terms adsorption and absorption. Give one example of.
What is the difference between physisorption and chemisorption?
Write one similarity between Physisorption and Chemisorption
How does chemisorption vary with temperature?
Answer in one sentence:
Name type of adsorption in which vander Waals focres are present.
Adsorption increases when ____________.
In physisorption, adsorption is generally ____________.
The extent of adsorption increases with the ____________.
Physical adsorption of a gaseous species may change to chemical adsorption with ______.
In which of the following reactions heterogenous catalysis is involved?
(a) \[\ce{2SO2 (g) + O2 (g) ->[NO(g)] 2SO3 (g)}\]
(b) \[\ce{2SO2 (g) ->[Pt(s)] 2SO3 (g)}\]
(c) \[\ce{N2 (g) + 3H2 (g) ->[Fe(s)] 2NH3 (g)}\]
(d) \[\ce{CH3COOCH3 (l) + H2O (l) ->[HCI(l)] CH3COOH (aq) + CH3OH (aq)}\]
What is the role of activated charcoal in gas mask used in coal mines?
Assertion: Detergents with low CMC are more economical to use.
Reason: Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.
Which among the following is a false statement?
Assertion A : Activated charcoal adsorbs SO2 more efficiently than CH4.
Reason R : Gases with lower critical temperatures are readily adsorbed by activated charcoal.
In light of the above statements, choose the correct answer from the options given below.
Which of the following statements is not true about physisorption?
