Advertisements
Advertisements
प्रश्न
Derive the relation between the elevation of boiling point and molar mass of solute.
Advertisements
उत्तर
The elevation in the boiling point is given by the expression `Δ"T"_"b" = "K"_"b" ."m"` .....(1)
The molality is given by the expression m = `"W"_2/("M"_2 . "W"_1)` ...(2)
Substitute equation (2) in equation (1)
`Δ"T"_"b" = "K"_"b" . "W"_2/("M"_2 . "W"_1`
APPEARS IN
संबंधित प्रश्न
8 g of glucose, C6H12O6 (Molar Mass = 180 g mol−1) is dissolved in 1 kg of water in a sauce pan. At what temperature will this solution boil?
(Kb for water = 0.52 K kg mol−1, boiling point of pure water = 373.15 K)
Calculate the boiling point of solution when 4g of MgSO4 (M= 120 g mol-1) was dissolved in 100g of water, assuming MgSO4 undergoes complete ionization. (Kb for water = 0.52 K kgmol-1)
Out of 1 M glucose and 2 M glucose, which one has a higher boiling point and why?
Define the following term:
Colligative properties
Account for the following :
H2S has lower boiling point than H2O.
Account for the following :
H2S has lower boiling point than H2O.
Arrange the following increasing order of their boiling point:
CH3CH2OH, CH3CHO, CH3–O–CH3
Arrange the following in increasing order of boiling points:
(CH3)3 N, C2 H5 OH, C2 H5 NH2
0.450 g of urea (mol. wt. 60) in 22.5 g of water show 0.170°C of elevation in boiling point. The molal elevation constant of water is:
Exactly 1 g of urea dissolved in 75 g of water gives a solution that boils at 100.114°C at 760 torrs. The molecular weight of urea is 60.1. The boiling point elevation constant for water is:
Which of the following aqueous solutions should have the highest boiling point?
The unit of ebulioscopic constant is ______.
Why is it not possible to obtain pure ethanol by fractional distillation? What general name is given to binary mixtures which show deviation from Raoult’s law and whose components cannot be separated by fractional distillation. How many types of such mixtures are there?
Calculate the molal elevation constant for water given that 0.2 molal solution of non-volatile and non-electrolyte solute increases the boiling point of water by 0.104 K.
The boiling point to a solution containing 50 gm of a non-volatile solute in 1 kg of solvent is 0.5° higher than that of pure solvent. Determine the molecular mass of the solute (give molecular mass of solvent) = 78 g mol–1 and kb for solvent = 2.53 km–1)
Assertion (A): Elevation in boiling point is a colligative property.
Reason (R): The lowering of vapour pressure of solution causes elevation in boiling point.
Calculate the boiling point elevation for a solution prepared by adding 10 g of MgCl2 to 200 g of water, assuming MgCl2 is completely dissociated.
(Kb for Water = 0.512 K kg mol−1, Molar mass MgCl2 = 95 g mol−1)
Which of the following aqueous solution will have the highest boiling point?
Which of the following aqueous solutions will exhibit the highest boiling point?
