हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Calculate the ‘spin only’ magnetic moment of M⁢2+(aq) ion (Z = 27).

Advertisements
Advertisements

प्रश्न

Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{( aq)}}\] ion (Z = 27).

संख्यात्मक
Advertisements

उत्तर

The electronic configuration of the M atom (Z = 27) is [Ar] 3d7 4s2.

∴ Electronic configuration of M2+ = [Ar] 3d7

i.e., 

↑↓ ↑↓

So it has three unpaired electrons.

∴ The spin-only magnetic moment is calculated by using the formula,

µ = `sqrt (n(n + 2))`

= `sqrt (3(3 + 2))`

= `sqrt 15`

= 3.87 B.M.

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 4: The d-block and f-block Elements - Intext Question [पृष्ठ १०३]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 4 The d-block and f-block Elements
Intext Question | Q 4.8 | पृष्ठ १०३

संबंधित प्रश्न

Account for the following:

Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Write the element which shows maximum number of oxidation states. Give reason.


Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.


Write balanced chemical equations for the conversion of `CrO_4^(2-)` to `Cr_2O_7^(2-)` in acidic medium and `Cr_2O_7^(2-)` to `CrO_4^(2-)`
 in basic medium.


Why do transition metal ions possess a great tendency to form complexes?


The paramagnetic character in the 3d-transition series elements increases up to Mn and then decreases.


Why do transition metals exhibit higher enthalpy of atomization? 


When \[\ce{KMnO4}\] solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because ______.


Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. Which of the following is not the characteristic property of interstitial compounds?


A solution of \[\ce{KMnO4}\] on reduction yields either a colourless solution or a brown precipitate or a green solution depending on pH of the solution. What different stages of the reduction do these represent and how are they carried out?


Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:

(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)

Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.


It has been observed that first ionization energy of 5 d series of transition elements are higher than that of 3d and 4d series, explain why?


The element with atomic number 53 belongs to


Why is the `"E"_(("V"^(3+)//"V"^(2+)))^"o"` value for vanadium comparatively low?


The value of Δ0 for \[\ce{RhCl^{3-}6}\] is 243 KJ/mol which wavelength of light will promote an electron from. The colour of the complex is ______.


Write the ionic equation for reaction of KI with acidified KMnO4.


A pair of coloured ions is ______.


For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:

Cr2+/Cr −0.9 V
Mn2+/Mn −1.2 V
Fe2+/Fe −0.4 V
Cr3/Cr2+ −0.4 V
Mn3+/Mn2+ +1.5 V
Fe3+/Fe2+ +0.8 V

Use this data to comment upon:

The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Atomic sizes


The E° value for the Mn2+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to the change of:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×