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प्रश्न
Assertion (A): Transition metals have high enthalpy of atomisation.
Reason (R): Greater number of unpaired electrons in transition metals results in weak metallic bonding.
विकल्प
Both (A) and (R) are true and (R) is the correct explanation of (A).
Both (A) and (R) are true, but (R) is not the correct explanation of (A).
(A) is true, but (R) is false.
(A) is false, but (R) is true.
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उत्तर
(A) is true, but (R) is false.
Explanation:
The assertion (A) is true: Transition metals exhibit a high enthalpy of atomization. This is owing to the strong metallic bonds found in these metals.
The reasoning (R) is false: The existence of unpaired electrons in transition metals causes stronger, rather than weaker, metallic bonding. The delocalization of d and s electrons across the metal lattice helps to form strong metallic connections.
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संबंधित प्रश्न
Account for the following:
Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.
How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.
Predict which of the following will be coloured in the aqueous solution?
Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ and Co2+. Give reasons for each.
Calculate the number of unpaired electrons in the following gaseous ions:
Mn3+, Cr3+, V3+ and Ti3+. Which one of these is the most stable in an aqueous solution?
Explain why Zn2+ salts are white whereas Cu2+ salts are coloured.
Generally transition elements form coloured salts due to the presence of unpaired electrons. Which of the following compounds will be coloured in solid-state?
EΘ of Cu is + 0.34V while that of Zn is – 0.76V. Explain.
Give reasons for the following statement:
Transition metals and most of their compounds show paramagnetic behaviour.
The oxidation state of Fe in [Fe(CO)5] is ______.
For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:
| Cr2+/Cr | −0.9 V |
| Mn2+/Mn | −1.2 V |
| Fe2+/Fe | −0.4 V |
| Cr3/Cr2+ | −0.4 V |
| Mn3+/Mn2+ | +1.5 V |
| Fe3+/Fe2+ | +0.8 V |
Use this data to comment upon:
The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
