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Answer the following in one or two sentences. Under what conditions the cell potential is called standard cell potential?

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प्रश्न

Answer the following in one or two sentences.

Under what conditions the cell potential is called standard cell potential?

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उत्तर

The cell potential measured under the standard conditions is called standard cell potential. The standard conditions chosen are 1 M concentration of a solution, 1 atm pressure for gases, solids and liquids in pure form and 25°C.

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अध्याय 5: Electrochemistry - Exercises [पृष्ठ ११८]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 5 Electrochemistry
Exercises | Q 2.07 | पृष्ठ ११८

संबंधित प्रश्न

Consider the half reactions with standard potentials.

  1. \[\ce{Ag^{\oplus}_{ (aq)} + e^{\ominus} -> Ag_{(s)}E^\circ = 0.8 V}\] 
  2. \[\ce{I2_{(s)} + 2e^\ominus -> 2I^{\ominus}_{(aq)} E^\circ = 0.53V}\]
  3. \[\ce{Pb^{2\oplus}_{(aq)} + 2e^{\ominus} -> Pb_{(s)} E^\circ = -0.13 V}\]
  4. \[\ce{Fe^{2\oplus} + 2e^{\ominus} -> Fe_{(s)} E^\circ = -0.44 V}\]

The strongest oxidising  and reducing agents respectively are ______.


Answer the following in one or two sentences.

Write Nernst equation. What part of it represents the correction factor for nonstandard state conditions?


Answer the following in brief.

Construct a galvanic cell from the electrodes Co3+ | Co and Mn2+/Mn. \[\ce{E{^{\circ}_{Co}}}\] = 1.82 V, \[\ce{E{^{\circ}_{Mn}}}\] = –1.18 V. Calculate \[\ce{E{^{\circ}_{cell}}}\]


Calculate emf of the cell at 25°C.

Zn(s) | Zn2+ (0.08 M) || Cr3+ (0.1 M) | Cr(s)

`E_(Zn)^0` = −0.76 V,  `E_(Cr)^0` = −0.74 V


What is cell voltage?


Calculate the voltage of the cell Sn(s) / Sn2+(0.02 M) // Ag+ (0.01 M) / Ag(s) at 25 °C.

Given: `"E"_"Sn"^circ` = - 0.136, `"E"_"Ag"^circ` = 0.800 V


Calculate `"E"_"cell"^circ` of the following galvanic cell:

Mg(s) / Mg2+(1 M) // Ag+ (1 M) / Ag(s) if `"E"_"Mg"^circ` = – 2.37 V and `"E"_"Ag"^circ` = 0.8 V. Write cell reactions involved in the above cell. Also mention if cell reaction is spontaneous or not.


Standard reduction electrode potentials of three metals A, B and C are +0.5 V, −3.0 V and −1.2 V respectively. The reducing power of these metals is ______.


The correct representation of Nernst's equation for half-cell reaction \[\ce{Cu^{2+} (aq) + e^- -> Cu^+(aq)}\] is ______.


Nernst equation for the following cell reaction at 298 K is:

\[\ce{Mg_{(s)} | Mg^{2+}_{( aq)} || Ag^+_{( aq)} | Ag_{(s)}}\]


Calculate \[\ce{E^0_{cell}}\] for the following cell.

\[\ce{Cr_{(s)} | Cr^{3+}_{( aq)} || Fe^{2+}){( aq)} | Fe_{(s)}}\]

Given: `"E"_("Cr"^(3+)//"Cr")^0` = −0.74 V,

`"E"_("Fe"^(2+)//"Fe")^0` = −0.44 V


Identify the strongest reducing agent from the data given below:

Element `"E"^0 ("V")`
Al −1.66
Fe −0.44
Hg +0.79
Cu +0.337

What is the standard emf of the following cell?

\[\ce{Ni_{(s)} | Ni^{2+}_{( aq)} || Au^{3+}_{( aq)} | Au_{(s)}}\]

if \[\ce{E^0_{Ni}}\] = −0.25 V, \[\ce{E^0_{Au}}\] = 1.50 V.


For the following cell, standard potential of copper electrode is 0.337 V and standard cell potential is 0.463 V.

\[\ce{Cu | Cu^{2+} (1 M) || Ag^+ (1 M)  Ag}\]

What is the standard potential of silver electrode?


The tendency of an electrode to lose electrons is known as ______


Define standard electrode potential.


The standard potential of the electrode Zn2+(0.02M) |Zn(s) is − 0.76 V. Calculate the electrode potential of the zinc electrode.


Calculate the emf of the following cell at 25°C.

Zn(s)|Zn2+(0.08 M) || Cu2+(0.l M) |Cu(s)

E0zn = − 0.76 V, E0cu = 0.36 V.


Write net cell reaction.


Write the value of `(2.303 RT)/F` in the Nernst equation?


Standard potential (E°) of

\[\mathrm{Zn_{(aq)}^{+2}+2e^{-}\longrightarrow Zn_{(s)}~is~-0.76~V}\]

What is standard potential of reaction 

\[2\mathrm{Zn}_{(\mathrm{s})}\longrightarrow2\mathrm{Zn}_{(\mathrm{aq})}^{+2}+4\mathrm{e}^{-}\] ?


Which from following formulae is used to obtain value of E°cell for a reaction taking place in Dry cell?


The cell potential for the following cell notation is approximately:

M(s) | M3+ (aq, 0.01 M) || N2+ (aq, 0.1 M) | N(s)

`E_(M^(3+)//M)^0` = 0.6 V and `E_(N^(2+)//N)^0` = 0.1 V


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