हिंदी

Answer the following in one or two sentences. State whether ΔS is positive, negative or zero for the reaction 2H(g) → H2(g). Explain.

Advertisements
Advertisements

प्रश्न

Answer the following in one or two sentences.

State whether ΔS is positive, negative or zero for the reaction 2H(g)  →  H2(g). Explain.

स्पष्ट कीजिए
Advertisements

उत्तर

ΔS is negative. Two moles of gaseous H atoms are converted into 1 mole of H2 gas. Thus, a disorder of the system decreases, and hence, entropy decreases, or ∆S is negative.

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 4: Chemical Thermodynamics - Exercises [पृष्ठ ८७]

APPEARS IN

बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 4 Chemical Thermodynamics
Exercises | Q 2.5 | पृष्ठ ८७

संबंधित प्रश्न

Answer the following in one or two sentences.

State second law of thermodynamics in terms of entropy.


Answer the following in one or two sentences.

If the enthalpy change of a reaction is ∆H how will you calculate the entropy of surroundings?


For a certain reaction ΔH° = 219 kJ and ΔS° = –21 J/K. Determine whether the reaction is spontaneous or nonspontaneous.


Equilibrium constant for a reaction is 20. What is the value of ΔG° at 300 K? (R = 8 x 10-3 kJ)


A system is changed from an initial state to a final state by a manner such that ∆H = Q. If the change from initial state to final state was made by a different path, then ____________.


Identify the INCORRECT statement.


For a process, entropy change of a system is expressed as ________.


For a reversible spontaneous change, ∆S is ____________.


Arrange the following in order of increasing entropy.

I. 1.0 mol H2O (298 K, 1 atm)

II. 1.0 mol H2O (270 K, 1 atm)

III. 1.0 mol H2O (400 K, 1 atm)


In which of the following, ∆S is positive?


For the following reaction:

\[\ce{Fe2O3_{(s)} + 3CO_{(g)} -> 2Fe_{(s)} + 3CO2_{(g)}}\]; ΔH0 = −29.8 kJ and ΔS0 = 15 J K−1. What is the value of \[\ce{ΔS_{(total)}}\] at 298 K?


Which of following is residual entropy of a substance?


Standard molar entropy is ______.


The H-H bond energy is 430 kJ mol-1 and Cl-Cl bond energy is 240 kJ mol-1. ΔfH for HCl is - 90 kJ, then H-Cl bond energy is ______.


When will be change in Gibb's free energy always negative?


A reaction is spontaneous at low temperatures but non-spontaneous at high temperatures. Which of the following is true for the reaction?


The criterion for a spontaneous process is ______.


Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are −382.64 kJ mol−1 and −145.6 JK−1 mol−1, respectively. Standard Gibb's energy change for the same reaction at 298 K is ______.


In which of the following reaction the value of Kp will be equal to Kc?


Dinitrogen and dioxygen combined to form nitrous oxide in equilibrium at 850 K. The equilibrium constant for this reaction is 0.56. If the equilibrium concentration of nitrous oxide gas is 3 × 10-3 M and both dinitrogen and dioxygen have the same concentration, then what will be the concentration of dinitrogen gas in M?


Identify whether the following pair have a larger entropy or not. If yes then Why?

O2{g) at 1 atm or O2(g) at 10 atm both at the same temperature.


Identify whether the following pair have a larger entropy or not. If yes then Why?

C2H5OH(l) or C2H5OH(g)


Write the relationship between Gibbs energy change for a process and total entropy change of system and surroundings.


For a certain reaction ΔH0 is −224 kJ and ΔS0 is −153 J K−1. At what temperature the change over from spontaneous to non-spontaneous will occur?


Calculate ΔG0 for the reaction

\[\ce{CH_{4(g)} + H_{2(g)}-> C2H_{6(g)}}\]

State whether the reaction is spontaneous or not. (Given: KP = 3.358 × 1017, T = 25° C, R = 8.314 × 10−3 kJK−1 moI−1)


Find out the value of equilibrium constant for the following reaction at 298 K, \[\ce{2NH3_{(g)} + CO2_{(g)} ⇌ NH2 - COONH2_{(aq)} + H2O_{(l)}}\] Gibbs Standard energy change 298 K = –13.6 kJ mol−1.


Define second law of thermodynamics.


The entropy of vaporisation of benzene is 85 J K−1 mol−1. When 117 g of benzene vaporises at its boiling point, what is the entropy change of the surroundings if the process is at equilibrium?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×