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प्रश्न
An organic compound A (molecular formula C2H4O2) reacts with Na metal to form a compound B and evolves a gas which burns with a pop sound. Compound A on treatment with an alcohol C in the presence of a little of concentrated sulphuric acid forms a sweet-smelling compound D (molecular formula C3H6O2). Compound D on treatment with NaOH solution gives back B and C. Identify A, B, C and
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उत्तर
The organic compound, A, with the molecular formula C2H4O2 is ethanoic acid (CH3COOH), as it evolves hydrogen with a pop sound on reacting with sodium.
When ethanoic acid reacts with sodium, a compound B called the sodium ethanoate (CH3COONa) is formed.
The alcohol, C, is methanol (CH3OH) which is treated with ethanoic acid in the presence of concentrated sulphuric acid to form a compound D.
The sweet-smelling compound D is methyl ethanoate (CH3COOCH3).
The chemical equation for the above stated reaction is as follows:
CH3OH + CH3COOH → CH3COOCH3 + H2O
When ethanoic acid reacts with alcohol in the presence of concentrated sulphuric acid, a sweet-smelling cmpound, ester is formed. Methyl ethanoate is a carboxylate ester, which on reaction with sodium hydroxide gives back methanol and Sodium ethanoate.
The chemical equation is as follows:
CH3COOCH3 + NaOH → CH3COONa + CH3OH
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संबंधित प्रश्न
While studying saponification reaction, a student measures the temperature of the reaction mixture and also finds its nature using blue/red litmus paper. On the basis of his observations the correct conclusion would be
(A) the reaction is exothermic and the reaction mixture is acidic.
(B) the reaction is endothermic and the reaction mixture is acidic.
(C) the reaction is endothermic and the reaction mixture is basic.
(D) the reaction is exothermic and the reaction mixture is basic.
Write the formulae of ethanoic acid.
The structural formula of an ester is :

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(1) Calcium bicarbonate
(2) Calcium hydroxide
(3) Calcium carbonate
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Reduction
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Ice like crystals formed on cooling an organic acid sufficiently.
Ethanoic acid _________.
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Shristi heated Ethanol with a compound A in presence of a few drops of concentrated sulphuric acid and observed a sweet smelling compound B is formed. When B is treated with sodium hydroxide it gives back Ethanol and a compound C.
- Identify A and C
- Give one use each of compounds A and B.
- Write the chemical reactions involved and name the reactions.
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Give the balanced chemical equation of the following reaction:
Neutralization of NaOH with ethanoic acid.
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