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Tamil Nadu Board of Secondary EducationHSC Science इयत्ता १२

HSC Science इयत्ता १२ - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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Assertion: Phenol is more acidic than ethanol.

Reason: Phenoxide ion is resonance stabilized.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

In the reaction \[\ce{Ethanol ->[PCl5] X ->[alc. KOH] Y ->[H2SO4/H2O][298 K] Z}\]. The ‘Z’ is

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

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The reaction can be classified as

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Isopropyl benzene on air oxidation in the presence of dilute acid gives ___________.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Assertion: Phenol is more reactive than benzene towards electrophilic substitution reaction

Reason: In the case of phenol, the intermediate arenium ion is more stabilized by resonance.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

HO CH2 CH2 – OH on heating with periodic acid gives ____________.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Which of the following compound can be used as antifreeze in automobile radiators?

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

The reaction is an example of

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

One mole of an organic compound (A) with the formula C3H8O reacts completely with two moles of HI to form X and Y. When Y is boiled with aqueous alkali it forms Z. Z answers the iodoform test. The compound (A) is ___________.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Among the following ethers which one will produce methyl alcohol on treatment with hot HI?

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

On reacting with neutral ferric chloride, phenol gives ____________.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Identify the product(s) is/are formed when 1-methoxy propane is heated with excess HI. Name the mechanism involved in the reaction.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Draw the major product formed when 1-ethoxyprop-1-ene is heated with one equivalent of HI.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Suggest a suitable reagent to prepare secondary alcohol with the identical group using a Grignard reagent.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

What is the major product obtained when two moles of ethyl magnesium bromide is treated with methyl benzoate followed by acid hydrolysis.

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Predict the major product, when 2-methyl-but-2-ene is converted into alcohol in the following method.

Acid catalysed hydration

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Predict the major product, when 2-methyl-but-2-ene is converted into alcohol in the following method.

Hydroboration

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Predict the major product, when 2-methyl-but-2-ene is converted into alcohol in the following method.

Hydroxylation using bayers reagent

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Arrange the following in the increasing order of their boiling point and give a reason for your ordering.

Butan-2-ol, Butan-1-ol, 2-methyl propane-2-ol

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined

Arrange the following in the increasing order of their boiling point and give a reason for your ordering.

Propan-1-ol, propan-1, 2, 3-triol, propan-1, 3-diol, propan-2-ol

[11] Hydroxy Compounds and Ethers
Chapter: [11] Hydroxy Compounds and Ethers
Concept: undefined >> undefined
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