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Tamil Nadu Board of Secondary EducationHSC Science इयत्ता ११

HSC Science इयत्ता ११ - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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Which of the following gases would you expect to deviate from ideal behavior under conditions of low-temperature F2, Cl2, or Br2? Explain.

[6] Gaseous State
Chapter: [6] Gaseous State
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Write the Van der Waals equation for a real gas. Explain the correction term for pressure and volume.

[6] Gaseous State
Chapter: [6] Gaseous State
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An ideal gas expands from the volume of 1 × 10–3 m3 to 1 × 10–2 m3 at 300 K against a constant pressure at 1 × 105 Nm–2. The work done is

[7] Thermodynamics
Chapter: [7] Thermodynamics
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The work done by the liberated gas when 55.85 g of iron (molar mass 55.85 g mol–1) reacts with hydrochloric acid in an open beaker at 25°C

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Define enthalpy of combustion.

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Define enthalpy of neutralization.

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Enthalpy of neutralization is always a constant when a strong acid is neutralized by a strong base: account for the statement.

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Derive the relation between ∆H and ∆U for an ideal gas. Explain each term involved in the equation.

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Bond order of a species is 2.5 and the number of electons in its bonding molecular orbital is formd to be 8 The no. of electons in its antibonding molecular orbital is

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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Non – Zero dipole moment is shown by ______.

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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Define bond order.

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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What is dipole moment?

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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Calculate the enthalpy change for the reaction \[\ce{Fe2O3 + 3CO -> 2Fe + 3CO2}\] from the following data.

\[\ce{2Fe + 3/2O2 -> Fe2O3}\]; ΔH = −741 kJ

\[\ce{C + 1/2O2 -> CO}\]; ΔH = −137 kJ

\[\ce{C + O2-> CO2}\]; ΔH = −394.5 kJ

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Linear form of carbondioxide molecule has two polar bonds. Yet the molecule has Zero dipole moment. Why?

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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The standard enthalpies of formation of SO2 and SO3 are −297 kJ mol−1 and −396 kJ mol−1 respectively. Calculate the standard enthalpy of reaction for the reaction: \[\ce{SO2 + 1/2O2 -> SO3}\]

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Define bond energy.

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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Explain resonance with reference to a carbonate ion.

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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Explain the bond formation in ethylene.

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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Explain the bond formation in acetylene.

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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CO2 and H2O both are triatomic molecule but their dipole moment values are different. Why?

[10] Chemical Bonding
Chapter: [10] Chemical Bonding
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