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MAH-MHT CET (PCM/PCB) entrance exam Question Bank Solutions

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At anode in the electrolysis of fused NaCl:

[15] Electrochemistry
Chapter: [15] Electrochemistry
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Calculate the quantity of electricity required to produce 0.42 g Ag at cathode during the electrolysis of AgNO3 solution. (Molar mass Ag = 108 g mol-1)

[15] Electrochemistry
Chapter: [15] Electrochemistry
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Calculate half-life of a first order reaction in minute if the rate constant is 1 × 10-3 s-1.

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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What is the number of unpaired electrons of nickel observed in \[\ce{[Ni(CN)4]^{2-}}\]?

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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Which of the following carboxylic acids is most reactive towards esterification?

[22] Aldehydes, Ketones, and Carboxylic Acids
Chapter: [22] Aldehydes, Ketones, and Carboxylic Acids
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Two moles of an ideal gas are allowed to expand from a volume of 10 dm3 to 2 m3 at 300 K against a pressure of 101.325 KPa. Calculate the work done.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Calculate the density of metal with molar mass 56 g mol- 1 that crystallises to form a bcc structure with edge length 288 pm.

[11] Solid State
Chapter: [11] Solid State
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A weak monobasic acid is 2% dissociated in its 0.01 M solution. What is the dissociation constant of a weak acid?

[13] Ionic Equilibrium
Chapter: [13] Ionic Equilibrium
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Identify unit cell from following having four particles in it

[11] Solid State
Chapter: [11] Solid State
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Both acetaldehyde and acetone will react with X reagent. Identify the reagent X.

[22] Aldehydes, Ketones, and Carboxylic Acids
Chapter: [22] Aldehydes, Ketones, and Carboxylic Acids
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Half-life of a first order reaction is 30 minutes and initial concentration of reactant is 0.1 M.

What is half-life of the reaction if initial concentration of reactant is doubled? 

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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Which is the relation between half life and rate constant for a zero order?

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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The final product in the following sequence of reaction is

[22] Aldehydes, Ketones, and Carboxylic Acids
Chapter: [22] Aldehydes, Ketones, and Carboxylic Acids
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Consider the following reaction.

\[\ce{SO2(g) + 1/2 O2(g) <=>[K1] SO3(g)}\]

\[\ce{2SO3(g)<=>[K2] 2SO2(g) + O2(g)}\]

What is the relation between K1 and K2?

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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A radioactive isotope decayed to 17/32 of its original mass after 60 minutes. Find the half-life of this radioisotope.

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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An element with molar mass 2.7 × 10-2 kg/mol. Forms a cubic units cell with edge length of 405 pm. If the density is 2.7 × 103 kg/m3. Find the nature of a cubic unit cell.

[11] Solid State
Chapter: [11] Solid State
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What is the density of potassium, if it has a bcc structure with edge length 4Å?
(Atomic mass of K = 39)

[11] Solid State
Chapter: [11] Solid State
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What is the rate constant of a first order reaction if 0.08 mole of reactant reduces to 0.02 mole in 23.03 minutes?

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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At room temperature, polonium Crystallises in a primitive cubic unit cell. If a = 3.36 Å. Calculate the theoretical density of polonium. [It's atomic weight is 209 g/mol.]

[11] Solid State
Chapter: [11] Solid State
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The IUPAC name of the coordination compound \[\ce{[Co(H2O)2 (NH3)4]Cl3}\] is ______.

[19] Coordination Compounds
Chapter: [19] Coordination Compounds
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