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Which stoichiometric defect decreases the density of the crystal?
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Define the following terms: Secondary batteries
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What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?
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What type of stoichiometric defect is shown by:
(i) ZnS
(ii) AgBr
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Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water.
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In the button cells widely used in watches and other devices, the following reaction takes place:
\[\ce{Zn_{(s)} + Ag2O_{(s)} + H2O_{(l)} -> Zn{^{2+}_{(aq)}} + 2Ag_{(s)} + 2OH^-_{ (aq)}}\]
Determine ΔrG° and E° for the reaction.
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Comment on the statement that “colloid is not a substance but a state of substance”.
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What are the different oxidation states exhibited by the lanthanoids?
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Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
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Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.
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Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.
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Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.
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The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
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Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.
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Write the electronic configuration of the element with the atomic number 61.
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How do you explain the amphoteric behaviour of amino acids?
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Draw the structure of the given derivative.
Acetaldehydedimethylacetal
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Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
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Which of the following is an appropriate set of reactants for the preparation of 1-methoxy-4-nitrobenzene and why?
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| (i) | (ii) |
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