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JEE Main entrance exam Question Bank Solutions

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The Gibb's energy change (in J) for the given reaction at [Cu2+] = [Sn2+] = 1 M and 298 K is ______.

\[\ce{Cu(s) + Sn^{2+}(aq) -> Cu^{2+}(aq) + Sn(s)}\]

`["E"_("Sn"^(2+)//"Sn")^0 = -0.16 "V", "E"_("Cu"^(2+)//"Cu")^0 = 0.34 "V", "Take F" = 96500  "C mol"^-1]`

[8] Redox Reactions and Electrochemistry
Chapter: [8] Redox Reactions and Electrochemistry
Concept: undefined >> undefined

Which type of isomerism can not be shown by benzaldoxime?

[21] Hydrocarbons
Chapter: [21] Hydrocarbons
Concept: undefined >> undefined

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The equilibrium constant at 25°C for the given cell is:

Zn | Zn2+ (1M) | | Ag+ (1M) |

Ag is ______ × 1052.

Given that

\[\ce{E^0_{Zn/Zn^{2+}}}\] = 0.76 V

and \[\ce{E^0_{Ag/Ag^{+}}}\] = −0.80 V

[8] Redox Reactions and Electrochemistry
Chapter: [8] Redox Reactions and Electrochemistry
Concept: undefined >> undefined

The e.m.f. of cell Zn | ZnSO4 | | CuSO4 | Cu at 25°C is 0.03 V and the temperature coefficient of e.m.f. is −1.4 × 10−4 V/K. The heat of reaction for the change taking place inside the cell is ______ kJ/mol.

[8] Redox Reactions and Electrochemistry
Chapter: [8] Redox Reactions and Electrochemistry
Concept: undefined >> undefined

Volume of N2 at NTP required to form a monolayer on the surface of iron catalyst is 8.15 ml/g of the adsorbent. If each nitrogen molecule occupies 16 × 10−22 m2. The surface area of the 100 g adsorbent will be ______ × 1018 m2.

[10] Surface Chemistry
Chapter: [10] Surface Chemistry
Concept: undefined >> undefined

Acetamide is isomer of ______.

[21] Hydrocarbons
Chapter: [21] Hydrocarbons
Concept: undefined >> undefined

Dipole moment of HX is 2.59 × 10−30 coulomb-metre. Bond length of HX is 1.39 Å. The ionic character of molecule is ______%.

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
Concept: undefined >> undefined

Finely divided catalyst has greater surface area and has greater catalytic activity than a compact solid. If a total surface area of 6291456 cm2 is required for adsorption of gaseous reaction in a catalysed reaction, then the number of splits should be made of a cube exactly 1 cm in length is ______.
[Given : After each split new cubes of equal dimensions are formed.]

[10] Surface Chemistry
Chapter: [10] Surface Chemistry
Concept: undefined >> undefined

Which one of the following pairs are called position isomers?

[21] Hydrocarbons
Chapter: [21] Hydrocarbons
Concept: undefined >> undefined

The correct stereochemical name of

[21] Hydrocarbons
Chapter: [21] Hydrocarbons
Concept: undefined >> undefined

1000 g aqueous solution of CaCO3 contains 10 g of calcium carbonate. Concentration of the solution is ______.

[13] Hydrogen
Chapter: [13] Hydrogen
Concept: undefined >> undefined

The dipole moments of the given molecules are such that ______.

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
Concept: undefined >> undefined

Electrolytic reduction method is used for the extraction of ______.

[12] General Principles and Processes of Isolation of Metals
Chapter: [12] General Principles and Processes of Isolation of Metals
Concept: undefined >> undefined

In the above reaction if we take methylene chloride and isopropylidene chloride then products are ______.

[22] Organic Compounds Containing Halogens
Chapter: [22] Organic Compounds Containing Halogens
Concept: undefined >> undefined

The compound that will not give iodoform on treatment with alkali and iodine is ______.

[22] Organic Compounds Containing Halogens
Chapter: [22] Organic Compounds Containing Halogens
Concept: undefined >> undefined

The observed dipole-moment of HCl molecule is 1.03 D. If \[\ce{H - Cl}\] bond distance is 1.275 Å and electronic charge is 4.8 × 10-10 esu. What is the percent polarity of HCl?

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
Concept: undefined >> undefined

How many structural isomers possible of the molecular formula C3H6O (excluding enol form)?

[21] Hydrocarbons
Chapter: [21] Hydrocarbons
Concept: undefined >> undefined

The cell potential for the following cell

\[\ce{Pt|H2 (g)| H+ (aq)||Cu^{2+} (0.01 M)| Cu(s)}\]

is 0.576 Vat 298 K. The pH of the solution is ____. (Nearest integer)

[8] Redox Reactions and Electrochemistry
Chapter: [8] Redox Reactions and Electrochemistry
Concept: undefined >> undefined

The standard Gibbs energy for the given cell reaction in kJ mol-1 at 2'98 K is:

\[\ce{Zn(s) + Cu^{2+} (aq) -> Zn^{2+} (aq) + Cu(s)}\]

E° = 2 V at 298 K

(Faraday's constant, F = 96000 C mol-1)

[8] Redox Reactions and Electrochemistry
Chapter: [8] Redox Reactions and Electrochemistry
Concept: undefined >> undefined

For a spontaneous reaction, the ΔG, equilibrium constant (K) and `"E"_"cell"^circ` will be respectively.

[8] Redox Reactions and Electrochemistry
Chapter: [8] Redox Reactions and Electrochemistry
Concept: undefined >> undefined
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