मराठी
Tamil Nadu Board of Secondary EducationHSC Science Class 12

Revision: Surface Chemistry Chemistry HSC Science Class 12 Tamil Nadu Board of Secondary Education

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Definitions [4]

Define the term Catalysis.

The phenomenon of increasing the rate of a chemical reaction with the help of a catalyst is known as catalysis.

Define the term Inhibition.

The phenomenon in which the rate of a chemical reaction is reduced by an inhibitor is called inhibition.

Definition: Catalysis

catalyst is a substance that alters the rate of a chemical reaction without being consumed. The phenomenon is called catalysis.

Definition: Emulsions

Emulsions are colloidal solutions of two immiscible liquids in which one liquid acts as the dispersed phase and the other as the dispersion medium.

Key Points

Key Points: Types of Catalysis
Type Description
Homogeneous

Reactants and catalyst are in the same phase

\[\ce{\underset{}{2SO2(g) + O2(g)} ->[NO(g)][]\underset{}{2SO3(g)}}\]

Heterogeneous

Reactants and catalyst are in different phases 

\[\ce{\underset{}{N2(g) + 3H2(g)} ->[][Fe(s)]\underset{}{2NH3(g)}}\]

On the basis of the mechanism of catalysis:
Positive catalysis Catalyst enhances the rate of reaction
Negative catalysis Catalyst retards the rate of reaction
Auto-catalysis One of the products acts as catalyst
Induced catalysis One reaction induces the rate of another reaction
Key Points: Emulsions

Emulsions show all properties of sols. Their particle size is 1000 Å to 10,000 Å; they scatter light (Tyndall effect).

Types of Emulsions:

Feature Oil in Water (O/W) Water in Oil (W/O)
Dispersed phase Oil Water
Dispersion medium Water Oil
Continuous phase Water Oil
Miscibility Addition of water mixes with it Addition of oil mixes with it
Electrolyte effect Small amount makes it conducting No effect on conducting power
Emulsifiers used Water-soluble alkali metal soaps, metal sulphates Water-insoluble soaps (Zn, Al, Fe), alkaline earth metal soaps
Examples Milk, vanishing cream Butter, cream, cod liver oil
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