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प्रश्न
What is the difference between homogeneous and heterogeneous catalysis?
Differentiate between homogeneous and heterogeneous catalysis.
फरक स्पष्ट करा
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उत्तर
| Sr. No. | Homogeneous catalysis | Heterogeneous catalysis |
| 1. | In a catalysed reaction the reactants, products and catalyst are present in the same phase. | In a reaction, the catalyst is present in a different phase. i.e., the catalyst is not present in the same phase as that of reactants and products. |
| 2. | For example, \[\ce{2SO2_{(g)} + O2_{(g)} ->[NO_{(g)}] 2SO3_{(g)}}\] Hence NO act as catalyst. | For example, \[\ce{2SO2_{(g)} + O2_{(g)} ->[Pt_{(s)}] 2SO3_{(g)}}\] Hence Pt(s) act as catalyst. |
| 3. | Homogeneous catalysis is explained by intermediate compound formation theory. | Heterogeneous catalysis is explained by adsorption theory. |
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| List - I | List - II | ||
| (Processes/Reactions) | (Catalyst) | ||
| (A) | \[\ce{2SO2(g) + O2(g) -> 2SO3(g)}\] | (I) | Fe(s) |
| (B) | \[\ce{4NH3 (g) + 5O2(g) -> 4NO(g) + 6H2O (g)}\] | (II) | Pt (s) - Rh (s) |
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| (D) | \[\ce{Vegetable oil (l) + H2 -> Vegetable ghee (s)}\] | (IV) | Ni (s) |
Choose the correct answer from the options given below:
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| Catalysts | Process | ||
| (A) | TiCl4 | (i) | Wacker process |
| (B) | PdCl2 | (ii) | Ziegler-Natta polymerization |
| (C) | CuCl2 | (iii) | Contact process |
| (D) | V2O5 | (iv) | Deacon’s process |
