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तामिळनाडू बोर्ड ऑफ सेकेंडरी एज्युकेशनएचएससी विज्ञान इयत्ता १२

Two metals M1 and M2 have reduction potential values of −xV and +yV respectively. Which will liberate H2 and H2SO4.

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प्रश्न

Two metals M1 and M2 have reduction potential values of −xV and +yV respectively. Which will liberate H2 and H2SO4.

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उत्तर

Metals having negative reduction potential act as powerful reducing agents. Since M1 has – xV, therefore M1 easily liberates H2 in H2SO4. Metals having higher oxidation potential will liberate H2 from H2SO4. Hence, the metal M1 having +xV, oxidation potential will liberate H2 from H2SO4.

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पाठ 9: Electro Chemistry - Evaluation [पृष्ठ ६६]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
पाठ 9 Electro Chemistry
Evaluation | Q 16. | पृष्ठ ६६

संबंधित प्रश्‍न

How many faradays of electricity are required to produce 6 g of Mg from MgCl2?


A gas X at 1 atm is bubbled through a solution containing a mixture of 1 MY and 1 MZ at 25°C. If the reduction potential of Z > Y > X, then ______.


The quantity of charge required to obtain one mole of aluminium from Al2O3 is ______.


Match the terms given in Column I with the units given in Column II.

Column I Column II
(i) Λm (a) S cm-¹
(ii) ECell (b) m-¹
(iii) K (c) S cm2 mol-¹
(iv) G* (d) V

Match the items of Column I and Column II.

Column I Column II
(i) K (a) I × t
(ii) Λm (b) `Λ_m/Λ_m^0`
(iii) α (c) `K/c`
(iv) Q (d) `G^∗/R`

In a Daniel cell, ______.


Read the passage given below and answer the questions that follow:

Oxidation-reduction reactions are commonly known as redox reactions. They involve transfer of electrons from one species to another. In a spontaneous reaction, energy is released which can be used to do useful work. The reaction is split into two half-reactions. Two different containers are used and a wire is used to drive the electrons from one side to the other and a Voltaic/Galvanic cell is created. It is an electrochemical cell that uses spontaneous redox reactions to generate electricity. A salt bridge also connects to the half-cells. The reading of the voltmeter gives the cell voltage or cell potential or electromotive force. If \[\ce{E^0_{cell}}\] is positive the reaction is spontaneous and if it is negative the reaction is non-spontaneous and is referred to as electrolytic cell. Electrolysis refers to the decomposition of a substance by an electric current. One mole of electric charge when passed through a cell will discharge half a mole of a divalent metal ion such as Cu2+. This was first formulated by Faraday in the form of laws of electrolysis.
The conductance of material is the property of materials due to which a material allows the flow of ions through itself and thus conducts electricity. Conductivity is represented by k and it depends upon nature and concentration of electrolyte, temperature, etc. A more common term molar conductivity of a solution at a given concentration is conductance of the volume of solution containing one mole of electrolyte kept between two electrodes with the unit area of cross-section and distance of unit length. Limiting molar conductivity of weak electrolytes cannot be obtained graphically.

  1. Is silver plate the anode or cathode?  (1)
  2. What will happen if the salt bridge is removed?  (1)
  3. When does electrochemical cell behaves like an electrolytic cell?  (1)
  4. (i) What will happen to the concentration of Zn2+ and Ag+ when Ecell = 0.   (1)
    (ii) Why does conductivity of a solution decreases with dilution?  (1)
    OR
    The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S cm2mol-1. Calculate the conductivity of this solution.  (2)

On which electrode the oxidation reaction takes place?


What are electrochemical reactions?


State the term for the following:

Two metal plates or wires through which the current enters and leaves the electrolytic cell.


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