Advertisements
Advertisements
प्रश्न
Kp = 0.04 atm at 899 K for the equilibrium shown below. What is the equilibrium concentration of C2H6 when it is placed in a flask at 4.0 atm pressure and allowed to come to equilibrium?
\[\ce{C2H6 (g) ⇌ C2H4 (g) + H2 (g)}\]
Advertisements
उत्तर
Let p be the pressure exerted by ethene and hydrogen gas (each) at equilibrium.
Now, according to the reaction,
| C2H6(g) | ↔ | C2H4(g) | + | H2(g) | |
| Initial conc. | 4.0 atm | 0 | 0 | ||
| At equilibrium | 4.0 - p | p | p |
We can write,
`("p"_("C"_2"H"_4) xx "p"_("H"_2))/"p"_("C"_2"H"_6) = "K"_"p"`
`=> ("p" xx "p")/(4.0 - "p") = 0.04`
`=> "p"^2 + 0.16 - 0.04 "p"`
`=> "p"^2 + 0.04 "p" - 0.16 = 0`
Now `"p" = (- 0.04 +- sqrt((0.04)^2 - 4xx1xx (-0.16)))/(2xx1)`
`= (-0.04 +- 0.80)/2`
`= 0.76/2` (Taking positive value)
= 0.38
Hence, at equilibrium,
`["C"_2"H"_6] - 4 - "p"`
= 4 - 0.38
= 3.62 atm
संबंधित प्रश्न
What is Kc for the following equilibrium when the equilibrium concentration of each substance is: [SO2] = 0.60 M, [O2] = 0.82 M and [SO3] = 1.90 M?
\[\ce{2SO2(g) + O2(g) ⇌ 2SO3(g)}\]
Write the expression for the equilibrium constant, Kc for each of the following reactions:
\[\ce{2NOCl (g) ⇌ 2NO (g) + Cl2 (g)}\]
Write the expression for the equilibrium constant, Kc for the following reactions:
\[\ce{CH3COOC2H5(aq) + H2O(l) ⇌CH3COOH (aq) + C2H5OH (aq)}\]
One mole of H2O and one mole of CO are taken in 10 L vessel and heated to 725 K. At equilibrium, 40% of water (by mass) reacts with CO according to the equation,
\[\ce{H2O (g) + CO (g) ⇌ H2 (g) + CO2 (g)}\]
Calculate the equilibrium constant for the reaction.
What is the equilibrium concentration of each of the substances in the equilibrium when the initial concentration of ICl was 0.78 M?
\[\ce{2 ICl(g) ⇌ I2(g) + Cl2(g)}\]; KC = 0.14
Does the number of moles of reaction products increase, decrease or remain same when each of the following equilibria is subjected to a decrease in pressure by increasing the volume?
\[\ce{3Fe (s) + 4H2O (g) ⇌ Fe3O4 (s) + 4H2 (g)}\]
The value of Kc for the reaction 3O2 (g) ↔ 2O3 (g) is 2.0 ×10–50 at 25°C. If the equilibrium concentration of O2 in the air at 25°C is 1.6 ×10–2, what is the concentration of O3?
For the reaction \[\ce{H2 (g) + I2 (g) ⇌ 2HI (g)}\], the standard free energy is ∆GΘ > 0. The equilibrium constant (K ) would be ______.
On increasing the pressure, in which direction will the gas phase reaction proceed to re-establish equilibrium, is predicted by applying the Le Chatelier’s principle. Consider the reaction.
\[\ce{N2 (g) + 3H2 (g) ⇌ 2NH3 (g)}\]
Which of the following is correct, if the total pressure at which the equilibrium is established, is increased without changing the temperature?
Match standard free energy of the reaction with the corresponding equilibrium constant.
| Column I | Column II |
| (i) ∆GΘ > 0 | (a) K > 1 |
| (ii) ∆GΘ > 0 | (b) K = 1 |
| (iii) ∆GΘ = 0 | (c) K = 0 |
| (d) K < 1 |
For the reaction,
\[\ce{N2 + O2(g) ⇌ 2NO(g)}\]
the equilibrium constant is K1. The equilibrium constant is K2 for the reaction
\[\ce{2NO(g) + O2(g) ⇌ 2NO2(g)}\]
What is "K" for the reaction:
\[\ce{NO2(g) ⇌ 1/2 N2(g) + O2(g)}\]?
The stepwise formation of [Cu(NH3)4]2+ is given below:
\[\ce{Cu^{2+} + NH3 <=>[K1] [Cu(NH3)]^{2+}}\]
\[\ce{[Cu(NH3)]^{2+} + NH3 <=>[K2] [Cu(NH3)2]^{2+}}\]
\[\ce{[Cu(NH3)2]^{2+} + NH3 <=>[K3] [Cu(NH3)3]^{2+}}\]
\[\ce{[Cu(NH3)3]^{2+} + NH3 <=>[K4] [Cu(NH3)4]^{2+}}\]
The value of stability constants K1, K2, K3 and K4 are 104, 1.58 × 102, 5 × 103 and 102 respectively. The overall equilibrium constant for dissociation of [Cu(NH3)4]2+ is x × 10−12. The value of x is ______. (Rounded-off to the nearest integer)
An equilibrium system for the reaction between hydrogen and iodine to give hydrogen iodide at 765 K in a 5 litre volume contains 0.4 mole of hydrogen, 0.4 mole of iodine and 2.4 moles of hydrogen iodide.
\[\ce{H2 + I2 <=> 2HI}\]
The equilibrium constant for the reaction is:
Sulphide ion in alkaline solution reacts with solid sulphur to form polysulphide ions having formula, \[\ce{S^{2-}2}\], \[\ce{S^{2-}3}\], \[\ce{S^{2-}4}\], etc. if K1 = 12 for \[\ce{S + S^{2-} <=> S^{2-}2}\] and K2 = 132 for \[\ce{2S + S^{2-} <=> S^{2-}3}\], K3 = ______ for \[\ce{S + S^{2-}2 <=> S^{2-}3}\].
For which of the following Kp is less than Kc?
The decomposition of N2O4 to NO2 was carried out in chloroform at 280°C. At equilibrium, 0.2 mol of N2O4 and 2 × 10−3 mol of NO2 were present in 2 ℓ of the solution. The equilibrium constant for the reaction \[\ce{N2O4 <=> 2NO2}\] is ______.
