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Identify A, B, C and D. ethanoic acid→SOClX2A→Pd/BaSOX4B→NaOHC→ΔD

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प्रश्न

Identify A, B, C and D.

\[\ce{ethanoic acid ->[SOCl2] A ->[Pd/BaSO4] B ->[NaOH] C ->[][\Delta] D}\]

थोडक्यात उत्तर
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उत्तर

\[\begin{array}{cc}
\ce{\underset{(Ethanoic acid)}{CH3COOH} ->[SOCl2] \underset{\underset{(A)}{(Acetyl chloride)}}{CH3COCl} ->[Pd/BaSO4][H2] \underset{\underset{(B)}{(Acetaldehyde)}}{CH3CHO} + HCl ->[NaOH] \ce{CH3 - CH - CH2 - CHO} ->[-H2O][\Delta] \underset{\underset{(D)}{(Crotonaldehyde)}}{CH3 - CH = CH - CHO}}\\
\phantom{........................}|\\
\phantom{...........................}\ce{\underset{\underset{(C)}{(Aldol 3-hydroxy butanal)}}{OH}}
\end{array}\]

A CH3Cl Acetyl chloride
B CH3CHO Acetaldehyde
C \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CHO}\\
|\phantom{..........}\\
\ce{OH}\phantom{.......}
\end{array}\]
3-hydroxy butanal
D CH3 – CH = CH – CHO Crotonaldehyde
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पाठ 12: Carbonyl Compounds and Carboxylic Acids - Evaluation [पृष्ठ १९३]

APPEARS IN

सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
पाठ 12 Carbonyl Compounds and Carboxylic Acids
Evaluation | Q 5. | पृष्ठ १९३

संबंधित प्रश्‍न

Answer in brief.

Observe the following equation of reaction of Tollens' reagent with aldehyde. How do we know that a redox reaction has taken place? Explain.

\[\ce{R-CHO + 2Ag(NH_{3})^{+}_{2} + OH^{-}->[\triangle] R-CO{O}^{-} + 2Ag↓ + 4NH3 + 2H2O}\]


Write reactions for the action of the following reagents on p-chlorobenzaldehyde.

Phenyl hydrazine


\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{.................}\ce{R}\phantom{..}\ce{H}\phantom{................}\\ \phantom{...}\backslash\phantom{..................}\backslash/\phantom{..........}\phantom{.......}\\ \ce{C = O ->[H2NNH2][KOH/glycol] C + N2 + H2O}\\ \phantom{}/\phantom{............}\phantom{.......}/\phantom{}\backslash\phantom{...............}\\ \phantom{}\ce{R}\phantom{..................}\ce{R}\phantom{..}\ce{H}\phantom{...............} \end{array}\]

Reaction is called ____________.


Which of the following is a Wolf - Kishner reduction?


Which one of the following undergoes reaction with 50% sodium hydroxide solution to give the corresponding alcohol and acid.


Complete the following reaction.

\[\begin{array}{cc}
\ce{CH3 - CH2 - CH2 - C - CH3 ->[HO - CH2 - CH2 - CH2 - OH][dry HCl] ?}\\
||\phantom{.........}\\
\ce{O}\phantom{.........}
\end{array}\]


How will you prepare cinnamic acid from benzaldehyde?


A substance C4H10O yields on oxidation a compound, C4H8O which gives an oxime and a positive iodoform test. The original substance on treatment with a conc. H2SO4 gives C4H8. The structure of the compound is ______.


Which of the following is not correctly matched?


Write the structure of the products obtained from the following ketones by action of hydrazine in presence of strong base KOH.


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