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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Draw a Neat and Well Labelled Diagram of Primary Reference Electrode. - Chemistry

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प्रश्न

Draw a neat and well labelled diagram of primary reference electrode.

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उत्तर

Primary reference electrode:

                  Standard Hydrogen Electrode
                 (Primary Reference Electrode)

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2015-2016 (March)

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संबंधित प्रश्‍न

Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer 

Element

Al(s)

Cu(s)

Cl(aq)

Ni(s)

 

Eo

-1.66V

0.34V

1.36V

-0.26V

 


The standard e.m.f of the following cell is 0.463 V

`Cu|Cu_(1m)^(++)`

What is the standard potential of Cu electrode?

(A) 1.137 V

(B) 0.337 V

(C) 0.463 V

(D) - 0.463 V


Calculate E°cell for the following reaction at 298 K:

2Al(s) + 3Cu+2(0.01M) → 2Al+3(0.01M) + 3Cu(s)

Given: Ecell = 1.98V


Calculate emf of the following cell at 25°C:

\[\ce{Sn/Sn^2+ (0.001 M) || H+ (0.01 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]

Given: \[\ce{E^\circ(Sn^2+/sn) = -0.14 V, E^\circ H+/H2 = 0.00 V (log 10 = 1)}\]


Calculate e.m.f of the following cell at 298 K:

2Cr(s) + 3Fe2+ (0.1M) → 2Cr3+ (0.01M) + 3 Fe(s)

Given: E°(Cr3+ | Cr) = – 0.74 VE° (Fe2+ | Fe) = – 0.44 V


Calculate emf of the following cell at 25 °C :

Fe|Fe2+(0.001 M)| |H+(0.01 M)|H2(g) (1 bar)|Pt (s)

E°(Fe2+| Fe)0.44 V E°(H+ | H20.00 V


Given the standard electrode potentials,

K+/K = −2.93 V, Ag+/Ag = 0.80 V,

Hg2+/Hg = 0.79 V

Mg2+/Mg = −2.37 V, Cr3+/Cr = −0.74 V

Arrange these metals in their increasing order of reducing power.


In the representation of the galvanic cell, the ions in the same phase are separated by a _______.


Draw a neat and labelled diagram of the lead storage battery.


Galvanic or a voltaic cell converts the chemical energy liberated during a redox reaction to ____________.


Standard electrode potential is measured taking the concentrations of all the species involved in a half-cell is ____________.


Standard hydrogen electrode operated under standard conditions of 1 atm Hpressure, 298 K, and pH = 0 has a cell potential of ____________.


Which cell will measure standard electrode potential of copper electrode?


Using the data given below find out the strongest reducing agent.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖` = 1.33 V  `"E"_("Cl"_2//"Cl"^-) = 1.36` V

`"E"_("MnO"_4^-//"Mn"^(2+))` = 1.51 V  `"E"_("Cr"^(3+)//"Cr")` = - 0.74 V


Use the data given in below find out which of the following is the strongest oxidising agent.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V


The positive value of the standard electrode potential of Cu2+/Cu indicates that:

(i) this redox couple is a stronger reducing agent than the H+/H2 couple.

(ii) this redox couple is a stronger oxidising agent than H+/H2 .

(iii) Cu can displace H2 from acid.

(iv) Cu cannot displace H2 from acid.


Which reference electrode is used to measure the electrode potential of other electrodes?


Represent the cell in which the following reaction takes place.The value of E˚ for the cell is 1.260 V. What is the value of Ecell?

\[\ce{2Al (s) + 3Cd^{2+} (0.1M) -> 3Cd (s) + 2Al^{3+} (0.01M)}\]


The standard electrode potential of the two half cells are given below:

\[\ce{Ni^{2+} + 2e^{-} -> Ni, E_0 = - 0.25 Volt}\]

\[\ce{Zn^{2+} + 2e^{-} -> Zn, E_0 = - 0.77 Volt}\]

The voltage of cell formed by combining the two half cells would be?


Standard reduction potentials (E°) of Cd2+, respectively which is the strongest reducing agent 


The emf of a galvanic cell, with electrode potential of Zn2+ = - 0.76 V and that of Cu2+ = 0.34 V, is ______.


A voltaic cell is made by connecting two half cells represented by half equations below:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\], E0 = − 0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = + 0.77 V

Which statement is correct about this voltaic cell?


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