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Answer the following Why salts of Sc3⊕, Ti4⊕, V5⊕ are colourless? - Chemistry

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प्रश्न

Answer the following

Why salts of Sc3⊕, Ti4⊕, V5⊕ are colourless?

टीपा लिहा
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उत्तर

i. Condensed electronic configurations of Sc3+, Ti4+, V5+ are: Sc3+: [Ar] 3d0 ; Ti4+: [Ar] 3d0 ; V5+: [Ar] 3d0

ii. The ions Sc3+, Ti4+ and V5+ have completely empty d-orbitals i.e., no unpaired electrons are present. Thus, their salts are colourless, as d-d transitions are not possible.

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Trends in Atomic Properties of the First Transition Series
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पाठ 8: Transition and Inner transition Elements - Exercises [पृष्ठ १९१]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 8 Transition and Inner transition Elements
Exercises | Q 2.03 | पृष्ठ १९१

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