Advertisements
Advertisements
प्रश्न
Answer in brief.
Obtain the expression for work done in chemical reaction.
Advertisements
उत्तर
- The work done by a system at constant temperature and pressure is given by
W = - Pext ΔV ....(1) - Assuming Pext = P,
W = - PΔV
= - P (V2 - V1)
W = - PV2 + PV1 .....(2) - If the gases were ideal, at constant temperature and pressure.,
PV1 = n1RT and PV2 = n2RT ....(3)
Substitution of equation (3) into equation (2) yields
W = - n2RT + n1RT
= - (n2 - n1) RT
= - Δng RT .....(4) - The equation (4) gives the work done by the system in chemical reactions.
APPEARS IN
संबंधित प्रश्न
Select the most appropriate option.
If the standard enthalpy of formation of methanol is –238.9 kJ mol–1 then entropy change of the surroundings will be _______.
Select the most appropriate option.
Bond enthalpies of H–H, Cl–Cl, and H–Cl bonds are 434 kJ mol–1, 242 kJ mol–1, and 431 kJ mol–1, respectively. Enthalpy of formation of HCl is _______.
Calculate the work done in the decomposition of 132 g of \[\ce{NH4NO3}\] at 100°C.
\[\ce{NH4NO3_{(s)} -> N2O_{(g)} + 2H2O_{(g)}}\]
State whether work is done on or by the system.
Calculate the amount of work done in the
1) Oxidation of 1 mole HCl(g) at 200 °C according to reaction.
4HCl(g) + O2(g) → 2Cl2(g) + 2H2O(g)
2) Decomposition of one mole of NO at 300 °C for the reaction
2NO(g) → N2(g) + O2(g)
Answer the following question.
When 6.0 g of O2 reacts with CIF as per
\[\ce{2ClF_{(g)} + O2_{(g)} -> Cl2O_{(g)} + OF2_{(g)}}\]
The enthalpy change is 38.55 kJ. What is the standard enthalpy of the reaction? (Δr H° = 205.6 kJ)
Calculate the standard enthalpy of formation of \[\ce{CH3OH_{(l)}}\] from the following data:
\[\ce{CH3OH_{(l)} + 3/2 O2_{(g)} -> CO2_{(g)} + 2H2O_{(l)} }\]; ΔrH° = − 726 kJ mol-1
\[\ce{C_{(graphite)} + O2_{(g)} -> CO2_{(g)}}\]; ΔcH° = −393 kJ mol−1
\[\ce{H2_{(g)} + 1/2 O_{(g)} -> H2O_{(l)}}\]; ΔfH° = −286 kJ mol−1
Calculate the work done and comment on whether work is done on or by the system for the decomposition of 2 moles of NH4NO3 at 100 °C
NH4NO3(s) → N2O(g) + 2H2O(g)
An ideal gas expands from the volume of 1 × 10–3 m3 to 1 × 10–2 m3 at 300 K against a constant pressure at 1 × 105 Nm–2. The work done is
Define enthalpy of neutralization.
Derive the relation between ∆H and ∆U for an ideal gas. Explain each term involved in the equation.
The standard enthalpies of formation of SO2 and SO3 are −297 kJ mol−1 and −396 kJ mol−1 respectively. Calculate the standard enthalpy of reaction for the reaction: \[\ce{SO2 + 1/2O2 -> SO3}\]
The standard enthalpy of formation of ammonia is −46.0 kJ mol−1. The enthalpy change for the reaction:
\[\ce{2NH3_{(g)} -> 2N2_{(g)} + 3H2_{(g)}}\] is ____________.
For which of the following ∆U = ∆H?
The difference between heats of reaction at constant pressure and at constanl volume for the reaction
\[\ce{2C6H6_{(l)} + 15O2_{(g)} -> 12CO2_{(g)} + 6H2O_{(l)}}\] at 25°C in kJ
Identify the equation in which change in enthalpy is equal to change in internal energy.
When 4 g of iron is burnt to ferric oxide at constant pressure, 29.28 kJ of heat is evolved. What is the enthalpy of formation of ferric oxide?
(Atomic mass of Fe = 56)
The enthalpy change for two reactions are given by the equations
\[\ce{2Cr_{(s)} + 1.5 O2_{(g)} -> Cr2O3_{(s)}}\];
∆H1 = −1130 kJ ............(i)
\[\ce{C_{(s)} + 0.5 O2_{(g)} -> CO_{(g)}}\];
∆H2 = −110 kJ .........(ii)
What is the enthalpy change, in kJ, for the following reaction?
\[\ce{3C_{(s)} + Cr2O3_{(s)} -> 2Cr_{(s)} + 3CO_{(g)}}\]
In which of the following reactions does the heat change represent the heat of formation of water?
If 2 kJ of heat is released from system and 6 kJ of work is done on the system, what is enthalpy change of system?
For the reaction, \[\ce{N_{2(g)} + 3H_{2(g)} -> 2NH_{3(g)}}\], ΔH is equal to ______.
What is the amount of work done when 0.5 mole of methane, CH4 (g), is subjected to combustion at 300 K? (Given, R = 8.314 JK-1mol-1)
Calculate ΔU if 2 kJ heat is released and 10 kJ of work is done on the system.
Define enthalpy.
Calculate the standard entropy change of the surrounding if standard enthalpy of formation of methyl alcohol is –240 kJ mol-1.
