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Chemistry
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Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Suppose an organism has 20 g of Carbon-14 at its time of death. Approximately how much Carbon-14 remains after 10,320 years? (Given antilog 0.517 = 3.289)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Approximately how old is a fossil with 12 g of Carbon-14 if it initially possessed 32 g of Carbon-14? (Given log 2.667 = 0.4260)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

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Which radioactive isotope would have the longer half-life 15O or 19O? (Given rate constants for 15O and 19O are 5.63 × 10–3 s–1 and k = 2.38 × 10–2 s–1 respectively.)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Arrhenius equation can be represented graphically as follows:

The (i) intercept and (ii) slope of the graph are:

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

A first-order reaction takes 69.3 min for 50% completion. What is the time needed for 80% of the reaction to get completed? (Given: log 5 = 0.6990, log 8 = 0.9030, log 2 = 0.3010)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Explain how and why will the rate of reaction for a given reaction be affected when the temperature at which the reaction was taking place is decreased.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Give reasons for the following observation:

pKb of aniline is lower than the m-nitroaniline.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Explain the following reaction:

Wolff-Kishner reduction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Observe the graph shown in figure and answer the following questions:


Write the relationship between k and t1/2 (half-life period)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Account for the following:

Arrange the following compounds in the increasing order of their basic strength in aqueous solution: CH3NH2,(CH3)3N,(CH3)2NH

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Explain the following reactions:

Clemmensen reaction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the main product in the following reaction:

\[\ce{CH3CH2CHO ->[Zn(Hg)/Conc. HCl]}\]

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Arrange the following compounds in increasing order of their boiling points:

CH3CH2OH, CH3−CHO, CH3−COOH

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

A first-order reaction is 50% complete in 30 minutes at 300 K and in 10 minutes at 320 K. Calculate activation energy (Ea) for the reaction. [R = 8.314 J K−1 mol−1]

[Given: log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021]

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Calculate the ΔrG0 and log Kc, for the given reaction at 298 K:

\[\ce{Ni_{(s)} + 2Ag^+_{( aq)} <=> Ni^{2+}_{( aq)} + 2Ag_{(s)}}\]

Given: `"E"_("Ni"^(2+)//"Ni")^0` = −0.25 V, `"E"_("Ag"^+//"Ag")^0` = +0.80 V, 1F = 96500 C mol−1.

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Among the following, which has the highest value of pKb?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

What happens to the rate constant k and activation energy Ea as the temperature of a chemical reaction is increased? Justify.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Why is the boiling point of o-dichlorobenzene higher than p-dichlorobenzene, but the melting point of para-isomer is higher than ortho-isomer?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined
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