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Science (English Medium) कक्षा ११ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

5f, 6d, 7s, 7p

[2] Structure of Atom
Chapter: [2] Structure of Atom
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The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

4d, 4f, 5s, 5p

[2] Structure of Atom
Chapter: [2] Structure of Atom
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The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

5p, 5d, 5f, 6s, 6p

[2] Structure of Atom
Chapter: [2] Structure of Atom
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The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2. How is this configuration explained?

[2] Structure of Atom
Chapter: [2] Structure of Atom
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What is the difference between the terms orbit and orbital?

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Match the following species with their corresponding ground state electronic configuration.

Atom / Ion Electronic configuration
(i) \[\ce{Cu}\] (a) 1s2 2s2 2p6 3s2 3p6 3d10
(ii) \[\ce{Cu^{2+}}\] (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2
(iii) \[\ce{Zn^{2+}}\] (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1
(iv) \[\ce{Cr^{3+}}\] (d) 1s2 2s2 2p6 3s2 3p6 3d9
  (e) 1s2 2s2 2p6 3s2 3p6 3d3
[2] Structure of Atom
Chapter: [2] Structure of Atom
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Match the quantum numbers with the information provided by these.

Quantum number Information provided
(i) Principal quantum number (a) orientation of the orbital
(ii) Azimuthal quantum number (b) energy and size of orbital
(iii) Magnetic quantum number (c) spin of electron
(iv) Spin quantum number (d) shape of the orbital
[2] Structure of Atom
Chapter: [2] Structure of Atom
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Match the following

(i) Photon (a) Value is 4 for N shell
(ii) Electron (b) Probability density
(iii) ψ2 (c) Always positive value
(iv) Principal quantum number n (d) Exhibits both momentum and wavelength
[2] Structure of Atom
Chapter: [2] Structure of Atom
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Match species given in Column I with the electronic configuration given in Column II.

Column I Column II
(i) \[\ce{Cr}\] (a) [Ar]3d84s0
(ii) \[\ce{Fe^{2+}}\] (b) [Ar]3d104s1
(iii) \[\ce{Ni^{2+}}\] (c) [Ar]3d64s0
(iv) \[\ce{Cu}\] (d) [Ar] 3d54s1
  (e) [Ar]3d64s2
[2] Structure of Atom
Chapter: [2] Structure of Atom
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Which of the following property of water can be used to explain the spherical shape of rain droplets?

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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How does the surface tension of a liquid vary with increase in temperature?

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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The magnitude of surface tension of liquid depends on the attractive forces between the molecules. Arrange the following in increasing order of surface tension:

water, alcohol \[\ce{(C2H5OH)}\] and hexane \[\ce{[CH3(CH2)4CH3)]}\].

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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Name two phenomena that can be explained on the basis of surface tension.

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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Why does sharp glass edge become smooth on heating it upto its melting point in a flame? Explain which property of liquids is responsible for this phenomenon.

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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Explain the term ‘laminar flow’. Is the velocity of molecules same in all the layers in laminar flow? Explain your answer.

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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Consider the reactions given below. On the basis of these reactions find out which of the algebric relations given in options (i) to (iv) is correct?

(a) \[\ce{C (g) + 4 H (g) -> CH4 (g); ∆_rH = xkJ mol^{-1}}\]

(b) \[\ce{C (graphic) + 2H2 (g) -> CH4 (g); ∆_rH = ykJ mol^{-1}}\]

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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One mole of acetone requires less heat to vapourise than 1 mol of water. Which of the two liquids has higher enthalpy of vapourisation?

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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The enthalpy of atomisation for the reaction \[\ce{CH4(g) -> C(g) + 4H(g)}\] is 1665 kJ mol–1. What is the bond energy of \[\ce{C – H}\] bond?

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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Use the following data to calculate \[\ce{∆_{lattice}H^Θ}\] for \[\ce{NaBr}\].

\[\ce{∆_{sub}H^Θ}\] for sodium metal = 108.4 kJ mol–1

Ionization enthalpy of sodium = 496 kJ mol–1

Electron gain enthalpy of bromine = – 325 kJ mol–1

Bond dissociation enthalpy of bromine = 192 kJ mol–1

\[\ce{∆_fH^Θ}\] for \[\ce{NaBr (s)}\] = – 325 kJ mol–1 

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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The net enthalpy change of a reaction is the amount of energy required to break all the bonds in reactant molecules minus amount of energy required to form all the bonds in the product molecules. What will be the enthalpy change for the following reaction.

\[\ce{H2(g) + Br(g) -> 2HBr(g)}\]

Given that Bond energy of \[\ce{H2, Br2}\] and \[\ce{HBr}\] is 435 kJ mol–1, 192 kJ mol–1 and 368 kJ mol–1 respectively.

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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