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What is the correct order of decreasing stability of the following cations.
| I. | \[\ce{CH3 - \overset{⊕}{C}H - CH3}\] |
| II. | \[\ce{CH3 - \overset{⊕}{C}H - OCH3}\] |
| III. | \[\ce{CH3 - \overset{⊕}{C}H - CH2 - OCH3}\] |
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Covalent bond can undergo fission in two different ways. The correct representation involving a heterolytic fission of CH3 – Br is:
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Write structures of various carbocations that can be obtained from 2-methylbutane. Arrange these carbocations in order of increasing stability.
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Match the intermediates given in Column I with their probable structure in Column II.
| Column I | Column II |
| (i) Free radical | (a) Trigonal planar |
| (ii) Carbocation | (b) Pyramidal |
| (iii) Carbanion | (c) Linear |
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Which of the following practices will not come under green chemistry?
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An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.
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An alkene ‘A’ contains three C–C, eight C–H σ bonds and one C–C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.
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The following data are obtained when dinitrogen and dioxygen react together to form different compounds:-
| Mass of dinitrogen | Mass of dioxygen | |
| (i) | 14 g | 16 g |
| (ii) | 14 g | 32 g |
| (iii) | 28 g | 32 g |
| (iv) | 28 g | 80 g |
(a) Which law of chemical combination is obeyed by the above experimental data?Give its statement.
(b) Fill in the blanks in the following conversions:
(i) 1 km = ______ mm = ______ pm
(ii) 1 mg = ______ kg = ______ ng
(iii) 1 mL = ______ L = _______ dm3
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How do you express the bond strength in terms of bond order?
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Compare the relative stability of the following species and indicate their magnetic properties;
`"O"_2, "O"_2^+, "O"_2^-`(superoxide), `"O"_2^(2-)`(peroxide)
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Calculate the bond order of N2, O2, `"O"_2^+`and `"O"_2^-`?
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Write IUPAC name of the product obtained by the ozonolysis of the following compound:
3,4-Dimethyl-hept-3-ene
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Write IUPAC name of the product obtained by the ozonolysis of the following compound:
2-Ethylbut-1-ene
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Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?
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What effect does branching of an alkane chain has on its boiling point?
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One of the reactions that takes place in producing steel from iron ore is the reduction of iron (II) oxide by carbon monoxide to give iron metal and CO2.
\[\ce{FeO (s) + CO (g) ↔ Fe (s) + CO2 (g)}\]; Kp= 0.265 at 1050 K.
What are the equilibrium partial pressures of CO and CO2 at 1050 K if the initial partial pressures are: pCO = 1.4 atm and `"p"_("co"_2)`= 0.80 atm?
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What are electrophiles and nucleophiles? Explain with examples.
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Identify the reagents shown in bold in the following equation as nucleophiles or electrophiles:
\[\ce{C6H6 + \underline{\text{CH}_3\overset{+}{\ce{C}}{\ce{O}}} -> C6H5COCH3}\]
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What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?
\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{H}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{D}
\end{array}\]
\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{D}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{H}\end{array}\]
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The reaction: \[\ce{CH_3CH_2I + KOH_{(aq)} -> CH_3CH_2OH + KI}\] is classified as ______.
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