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Define the following terms: Secondary batteries
Concept: Batteries >> Primary Batteries
On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]
(A) 1.0
(B) 13.5
(C) 0.50
(D) 0.75
Concept: Electrolytic Cells and Electrolysis - Introduction
Write any two uses of H2SO4
Concept: Electrolytic Cells and Electrolysis - Introduction
10.0 grams of caustic soda when dissolved in 250 cm3 of water, the resultant gram molarity of solution is _______.
(A) 0.25 M
(B) 0.5 M
(C) 1.0 M
(D) 0.1 M
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Construct a labelled diagram for the following cell:
`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`
Concept: Electrochemical Cells
Write any ‘two’ advantages of calomel electrode.
Concept: Relation Between Gibbs Energy Change and Emf of a Cell
Potential of saturated calomel electrode is-
Concept: Relation Between Gibbs Energy Change and Emf of a Cell
Draw neat labelled diagram of electrolytic refining of blister copper
Concept: Electrolytic Cells and Electrolysis - Introduction
The conductivity of 0.02 M AgNO3 at 25°C is 2.428 × 10−3 Ω−1 cm−1. What is its molar conductivity?
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 8
(D) 8 : 1
Concept: Electrolytic Cells and Electrolysis - Introduction
Explain Faraday’s second law of electrolysis
Concept: Electrolytic Cells and Electrolysis - Introduction
Define entropy.
Concept: Spontaneous (Irreversible) Process
Write electrode reaction and net cell reaction for fuel cell. Calculate e.m.f. of the following cell at 25 °C.
Standard reduction potential (SRP) of Zn and Cu are − 0.76 V and 0.334 V respectively
Concept: Batteries >> fuel cell
Write mathematical expression of molar conductivity of the given solution at infinite dilution.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Write cathode and anode reaction in a fuel cell.
Concept: Electrochemical Cells
In the hydrogen-oxygen fuel cell, the carbon rods are immersed in the hot aqueous solution of __
(a) KCl
(b) KOH
(c) H2SO4
(d) NH4Cl
Concept: Batteries >> fuel cell
How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride solution? (Given: Molar mass of Al = 27.0-gram mol–1)
Concept: Electrolytic Cells and Electrolysis - Introduction
Calculate the internal energy at 298K for the formation of one mole of ammonia, if the enthalpy change at constant pressure is – 42.0 kJ mol-1.
(Given: R = 8.314 J K-1 mol-1)
Concept: Chemical Thermodynamics and Energetic >> First Law of Thermodynamics
How many faradays of electricity are required to produce 6 g of Mg from MgCl2?
Concept: Electrochemical Cells
How much quantity of electricity in coulomb is required to deposit 1.346 × 10-3 kg of Ag in 3.5 minutes from AgNO3 solution?
( Given: Molar mass of Ag is 108 × 10-3 kg mol-1 )
Concept: Electrolytic Cells and Electrolysis - Introduction
