Definitions [6]
Explain Reversible reaction.
- Reactions which do not go to completion and occur in both directions simultaneously are called reversible reactions.
- Reversible reactions proceed in both directions. The direction from reactants to products is the forward reaction, whereas the opposite reaction from products to reactants is called the reverse or backward reaction.
- A reversible reaction is denoted by drawing in between the reactants and product a double arrow, one pointing in the forward direction and other in the reverse direction (⇌). e.g.
a. \[\ce{H_{2(g)} + I_{2(g)} ⇌ 2HI_{(g)}}\]
b. \[\ce{CH3COOH_{(aq)} + H2O_{(l)} ⇌ CH3COO^{-}_{ (aq)} + H3O^{+}_{ (aq)}}\]
Define pOH.
The pOH of a solution can be defined as the negative logarithm to the base 10, of the molar concentration of OH− ions in solution.
pOH = -log10[OH-]
Define pH.
The pH of a solution is defined as the negative logarithm to the base 10, of the concentration of H+ ions in solution in mol dm–3.
pH is expressed mathematically as
pH = -log10 [H+] or pH = -log10 [H3O+]
pH scale is a scale for measuring the hydrogen ion concentration in a solution.
Define Acidic buffer solution.
A solution containing a weak acid and its salts with strong base is called an acidic buffer solution.
Define buffer solution.
A buffer solution is defined as a solution which resists drastic changes in pH when a small amount of strong acid, strong base, or water is added to it.
Key Points
- The pH scale (0–14) measures the concentration of H⁺ ions in a solution; values < 7 indicate acids, > 7 indicate bases, and 7 is neutral.
- A universal indicator shows different colours at different pH levels, helping to determine the strength of an acid or base.
- Strong acids/bases produce more H⁺ or OH⁻ ions in solution, while weak acids/bases produce fewer ions at the same concentration.
Concepts [46]
- Concept of Equilibrium
- Equilibrium in Physical Processes
- Solid-liquid Equilibrium
- Liquid-vapour Equilibrium
- Solid - Vapour Equilibrium
- Equilibrium Involving Dissolution of Solid in Liquids
- Equilibrium Involving Dissolution of Gases in Liquids
- General Characteristics of Equilibria Involving Physical Processes
- Equilibrium in Chemical Processes - Dynamic Equilibrium
- Law of Chemical Equilibrium and Equilibrium Constant
- Homogeneous and Heterogenous Equilibria
- Applications of Equilibrium Constants
- Predicting the Extent of a Reaction
- Predicting the Direction of the Reaction
- Calculating Equilibrium Concentrations
- Relationship Between Equilibrium Constant K, Reaction Quotient Q and Gibbs Energy G
- Factors affecting equilibria
- Effect of Inert Gas Addition
- Introduction of Chemical Equilibrium
- Effect of Concentration Change
- Effect of Temperature Change
- Effect of Pressure Change
- Effect of change in volume
- Effect of Catalyst
- Ionic Equilibrium in Solution
- Concept of Acid, Base, and Salt
- Arrhenius Concept of Acids and Bases
- The Brönsted-Lowry Acids and Bases
- Lewis Acids and Bases
- Ionization of Acids and Bases
- The Ionization Constant of Water and Its Ionic Product
- The pH Scale
- Ionization Constants of Weak Acids
- Ionization of Weak Bases
- Relation Between Ka and Kb
- Relation Between Ka and Kb
- Di- and Polybasic Acids and Di- and Polyacidic Bases
- Factors Affecting Acid Strength
- Hydrolysis of Salts and the Ph of Their Solutions
- Buffer Solutions
- Designing Buffer Solution
- Concept of Solubility Equilibria of Sparingly Soluble Salts
- Solubility Product Constant
- Common Ion Effect on Solubility of Ionic Salts
- Le Chatelier's Principle
- Common Ion Effect
