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Write a mathematical expression for Standard Cell Potential. - Chemistry

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प्रश्न

Write a mathematical expression for Standard Cell Potential.

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उत्तर

The standard cell potential can be written as:

`"E"_"cell"^0 = "E"_"red"^0  ("cathode") - "E"_"red"^0  ("anode")`

Omitting the subscript ‘red’, we have

`"E"_"cell"^0 = "E"^0  ("cathode") - "E"^0  ("anode")`

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Thermodynamics of Galvanic Cells
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अध्याय 5: Electrochemistry - Very short answer questions

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 5 Electrochemistry
Very short answer questions | Q 3

संबंधित प्रश्न

Answer the following in brief.

Using the relationship ΔG° of cell reaction and the standard potential associated with it, how will you show that the electrical potential is an intensive property?


Equilibrium constant of the reaction, \[\ce{2Cu^{\oplus}_{(aq)} -> Cu^{2\oplus}_{(aq)} + Cu_{(s)}}\] is 1.2 × 106. What is the standard potential of the cell in which the reaction takes place?


What is the mass of copper metal produced at cathode during the passage of 2.03 A current through the CuSO4 solution for 1 hour. Molar mass of Cu = 63.5 g mol–1.


Derive the relationship between Gibbs energy of cell reaction and cell potential.


If entropy of a solid is greater than zero, at T = 0, it is called ______.


The standard emf of a galvanic cell involving cell reaction with n = 1 was found to be 0.592 V at 25°C. The equilibrium constant of the reaction would be ____________.


Standard hydrogen electrode (SHE) is a ______.


Consider the cell \[\ce{Al | Al^{3+} (1 M) || Sn^{2+} (1 M) | Sn}\], \[\ce{E^0_{Al}}\] = −1.66 V; \[\ce{E^0_{Fe}}\] = −0.136 V, ∆G0 for the above cell is ____________.


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`("E"_"Ni"^circ = - 0.25 "V" and "E"_"Al"^circ = 1.66 "V")`


Calculate standard Gibbs energy change at 25°C for the cell reaction.

\[\ce{Cd_{(s)} + Sn^{2+}_{ (aq)} -> Cd^{2+}_{ (aq)} + Sn_{(s)}}\]

\[\ce{E^0_{cd}}\] = –0.403 V, \[\ce{E^0_{Sn}}\] = –0.136 V


E0cell (Standard Potential of cell) for the following cell reaction is ______.

\[\ce{Cd_{(s)} + Sn^{2+}_{(aq)}-> Cd^{2+}_{(aq)} + Sn_{(s)}}\]

(E0Cd = − 0.403 V and E0Sn = − 0.136 V)


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