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Using the standard electrode potentials, predict if the reaction between the following is feasible: \\ce{Ag_{(s)}}\ and \\ce{Fe^{3+}_{( aq)}}\ - Chemistry

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प्रश्न

Using the standard electrode potentials, predict if the reaction between the following is feasible:

\[\ce{Ag_{(s)}}\] and \[\ce{Fe^{3+}_{( aq)}}\]

संख्यात्मक
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उत्तर

A reaction is possible if the value of `"E"_"cell"^Θ` is feasible.

The reaction is as follows –

\[\ce{Ag_{(s)} + Fe^{3+}_{( aq)} -> Ag^{+}_{( aq)} + Fe^{2+}_{( aq)}}\]

According to this the cell will be as follows –

\[\ce{Ag_{(s)} | Ag^{+}_{( aq)} || Fe^{3+}_{( aq)} | Fe^{2+}_{( aq)}}\]

∴ `"E"_("cell")^Θ = "E"_("Fe"^(3+)//"Fe"^(2+))^Θ - "E"_("Ag"^+//"Ag")^Θ`

= 0.77 − 0.80

= −0.03 V

Since the value of `"E"_"cell"^Θ` is negative, hence the reaction is not feasible.

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अध्याय 2: Electrochemistry - Exercises [पृष्ठ ६०]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 2 Electrochemistry
Exercises | Q 2.17 (iv) | पृष्ठ ६०

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