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प्रश्न
Standard electrode potential for Sn4+/Sn2+ couple is +0.15 V and that for the Cr3+/Cr couple is −0.74. These two couples in their standard state are connected to make a cell. The cell potential will be ______.
विकल्प
+0.89 V
+0.18 V
+1.83 V
+1.199 V
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उत्तर
Standard electrode potential for Sn4+/Sn2+ couple is +0.15 V and that for the Cr3+/Cr couple is −0.74. These two couples in their standard state are connected to make a cell. The cell potential will be +0.89 V.
Explanation:
Given: Sn4+/Sn2+ = +0.15 V
Cr3+/Cr = −0.74 V
Since Sn4+/Sn2+ has a higher potential, it acts as the cathode, and Cr3+/Cr acts as the anode.
Cell potential is calculated using:
\[\ce{E{^{\circ}_{cell}} = E{^{\circ}_{cathode}} - E{^{\circ}_{anode}}}\]
\[\ce{E{^{\circ}_{cell}}}\] = 0.15 − (−0.74)
= 0.15 + 0.74
= 0.89 V
